Sodium Bisulfite 25% ACS Grade

CAS
7631-90-5
Formula
NaHSO3
UN number
UN2693
$20.96
$20.96

1 Quart

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1 Quart About 10 inches tall

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Ships UPS Ground
Quantity
In Stock — ready to ship from our Taylor, TX warehouse Order by Mon-Thu 2 PM CT / Fri 12 PM CT — ships in 1–2 business days If it’s listed, it’s on our shelf. No backorders, no 4-week lead times. Why
Temporarily unavailable This item isn’t ready to ship right now. Call 512-365-6838 for restock timing.
  • No hazmat fees from us — you pay the carrier’s shipping rate, at cost
  • Gallon+ sizes ship as DOT-regulated hazmat, so carrier freight runs higher — how shipping works
  • Drums, totes & pails ship LTL freight — liftgate delivery available
  • PO / Net 30 for approved businesses · tax-exempt ordering supported

Sodium Bisulfite 25% ACS Grade

$20.96
Ball-and-stick model of Sodium bisulfite

Sodium Bisulfite

Active ingredient
sodium bisulfite, also known as sodium hydrogen sulfite · sodium bisulphite · sodium acid sulfite
CAS number
7631-90-5
Formula
NaHSO3
Molecular weight
104.06 g/mol
Grade
ACS Reagent Grade
Boiling point
100 to 103 °C (212 to 217 °F) (aqueous solution)

How it is classified for shipping

UN number
UN2693
Hazard class
8 Corrosive
Packing group
III

Proper shipping name Bisulfites, aqueous solutions, n.o.s. (Sodium bisulfite)

Hazards

Signal word Danger

  • Corrosive
  • Irritant

Summary only. Read the SDS and the container label for complete hazard and handling information.

SDS also in

Product quick facts

CAS 7631-90-5NaHSO3UN2693

Sodium Bisulfite 25% ACS Grade (CAS 7631-90-5) is an ACS reagent-grade with molecular formula NaHSO3 and a molecular weight of 104.06 g/mol, meeting American Chemical Society specifications for analytical use. Its active ingredient, sodium bisulfite, is also known as sodium hydrogen sulfite, sodium bisulphite and sodium acid sulfite. It ships as DOT Hazard Class 8. Alliance Chemical supplies this product in 7 container sizes from 1 Quart to 330 Gallon (16 pack options) with 1-2 business day shipping from Taylor, TX on in-stock orders, plus SDS and lot-specific Certificate of Analysis.

  • Pack sizes 7 container sizes (1 Quart to 330 Gallon) · 16 pack options
  • Purity / spec ACS Reagent Grade
  • Lead time In-stock orders placed by Mon-Thu 2 PM CT / Fri 12 PM CT typically ship within 1-2 business days.
  • Regional availability View state-by-state shipping pages
Forklift moving pallets in a warehouse

Stock footage.

How it ships.

Regulated products are packed, marked, and labeled for hazmat transport, from one quart to a pallet of drums.

  • Most stocked orders ship in 1–2 business daysOrder cutoff: Mon-Thu 2 PM CT / Fri 12 PM CT
  • Hazmat packing, marking, and labelingPacked by staff trained under DOT rule 49 CFR 172.704
  • UPS Ground for bottles, jugs, and up to three pailsLTL freight for four or more pails, drums, and totes. Liftgate on request.
  • Ships with
  • UPS
  • FedEx Freight
  • ABF Freight
  • R+L Carriers
  • Saia
  • Southeastern Freight Lines
  • XPO

Buying for a company or agency?

Pay by card at the listed price, or order on Net 30 terms once your credit is approved. For NSN and contract requirements, send an RFQ.

CAGE code
1LT50
UEI
DCTCZDY3BLD3
Primary NAICS
424690
Ownership
Woman-Owned
Federal supply
DLA Supplier
Terms
Net 30 on approved credit, W-9 on request
Gloved hands strapping four blue chemical drums to a pallet at a warehouse loading dock
Illustration.

Safety data sheets and certificates.

Find an SDS or TDS by product name or CAS number. Certificates of analysis are free on request.

Find an SDS or COA

Selected organizations we've supplied

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Why Sodium Bisulfite 25% Solution – Technical Grade

Sodium Bisulfite 25% Solution – Technical Grade (NaHSO3) is an aqueous, clear to pale yellow liquid formulated specifically for industrial and environmental operations requiring a ready-to-dose reducing agent. The exact 25% concentration provides an optimal balance between chemical activity and cold-weather handling stability, significantly lowering the risk of line crystallization and pumping failures often associated with higher saturation levels. Because it is delivered as a fully dissolved liquid, this technical grade chemical eliminates the hazardous dust generation, lengthy dissolution times, and incomplete mixing issues inherent to dry inorganic powders. The product is entirely soluble in water and alcohol, ensuring immediate dispersion and rapid reaction kinetics in time-sensitive industrial processes.

Best Applications for This Grade

  • Commonly applied in large-scale municipal and industrial wastewater treatment facilities as a rapid-acting dechlorination agent to neutralize free and combined chlorine residuals prior to final effluent discharge into natural waterways.
  • Functions as a targeted oxygen scavenger commonly applied in industrial boiler water systems, where it continuously reacts with dissolved oxygen to halt oxidative corrosion and extend the operational lifespan of internal metal pipes and heating surfaces.
  • Serves as a critical reducing agent commonly applied in metal finishing and electroplating facilities, specifically engineered to reduce hazardous hexavalent chromium to the easier-to-manage trivalent chromium state for subsequent precipitation and removal.
  • Commonly applied in textile bleaching and paper manufacturing processes as an antichlor, actively neutralizing residual peroxide or chlorine to halt the bleaching reaction and prevent ongoing degradation of the cellulose or fabric fibers.

When to Choose a Different Grade

  • If your operation processes high-volume water treatment and requires a more concentrated solution to reduce freight costs and minimize inventory footprint, evaluate Sodium Bisulfite 40%.
  • If your environmental application demands an oxidizing agent rather than a reducing compound, particularly for complex odor control or specialized water treatment protocols, consider Sodium Chlorite Flakes 80% - Technical Grade.
  • If your facility is better equipped to handle dry inorganic salts, or if your specific application involves photographic processing and cyanide neutralization, Sodium Thiosulfate is the appropriate alternative.
  • If your formulation requires a chelating agent to bind dissolved heavy metal ions in industrial cleaning solutions rather than a chemical reducer, Trisodium EDTA provides the necessary molecular structure.

Frequently Asked Questions About Sodium Bisulfite 25% ACS Grade

What is Sodium Bisulfite 25% ACS Grade and what is its chemical formula?
Sodium Bisulfite 25% ACS Grade is listed under CAS 7631-90-5 (PubChem reference search). The catalog formula is NaHSO3. The listed molecular weight is 104.06 g/mol. For solutions and blends, identity values may describe a constituent; consult the product SDS for composition.
What are the physical properties of Sodium Bisulfite 25% ACS Grade?
Catalog reference information for Sodium Bisulfite 25% ACS Grade: melting point: -9 to 0 °C (16 to 32 °F), freezing point (aqueous solution); boiling point: 100 to 103 °C (212 to 217 °F) (aqueous solution); reference values may describe a pure substance rather than the supplied concentration or blend. Confirm applicable conditions and specifications in the product documents; these values are not batch test results.
What grade and purity of Sodium Bisulfite 25% ACS Grade does Alliance Chemical offer?
Alliance Chemical lists Sodium Bisulfite 25% ACS Grade in ACS reagent grade. Check the product specification for the measurement basis and acceptance limits. A grade label alone does not establish certification or suitability for a regulated application. For batch results, request a COA using the product name and lot number.
What are common industrial applications of Sodium Bisulfite 25% ACS Grade?
To evaluate it for your process, compare the listed grade, concentration and product specifications with your requirements. Contact Alliance Chemical to confirm any application-specific documentation or certification before ordering.
What are the hazards of Sodium Bisulfite 25% ACS Grade and where do I find handling guidance?
Per its GHS classification (SDS Section 2), Sodium Bisulfite 25% ACS Grade carries the signal word Danger and the following hazard statements: H302 HARMFUL IF SWALLOWED; H318 CAUSES SERIOUS EYE DAMAGE; EUH031 CONTACT WITH ACIDS LIBERATES TOXIC GAS. Product-specific first aid, fire-fighting, spill response, handling, storage, exposure controls/PPE, and disposal guidance are in SDS Sections 4-8 and 13 — always consult the SDS before use. Download the SDS.
What is the DOT shipping classification for Sodium Bisulfite 25% ACS Grade?
The catalog transport entry lists UN2693, hazard class 8, packing group III. Consult SDS Section 14 and confirm the requirements for your selected pack size and shipping destination with Alliance Chemical.
How must Sodium Bisulfite 25% ACS Grade waste be disposed?
Consult SDS Section 13 for disposal information for Sodium Bisulfite 25% ACS Grade. Disposal requirements depend on the resulting waste, contamination and location. Have your site's responsible waste professional determine the appropriate waste classification and disposal method. View the SDS.
Does Alliance Chemical provide an SDS and COA for Sodium Bisulfite 25% ACS Grade?
Search the document library for Sodium Bisulfite 25% ACS Grade. The SDS is also available here. A sample COA describes specifications and does not establish the results for your shipment. To request a lot-specific COA or confirm document availability, contact Alliance Chemical with the product name and lot number.