Sodium Bisulfite 40% ACS Grade

Category : Salts

$25.00
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Customers who purchased Sodium Bisulfite 40% ACS Grade also bought:

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Sodium Bisulfite 40% ACS Grade

$25.00

Quick Answer

What is Sodium Bisulfite 40% ACS Grade used for, and what should buyers verify before ordering?

Sodium Bisulfite 40% ACS Grade is supplied at 39-41% in ACS Grade with UN 3265, DOT Class 8 . Buyers should confirm pack size, grade, SDS, COA needs, and freight requirements before purchase.

  • Assay: 39-41%
  • Grade: ACS Grade
  • UN number: UN 3265
  • DOT class: 8
  • Documents: SDS and lot-specific COA support
  • Shipping: UPS for small packs; LTL/FTL for pails, drums, totes, and bulk orders

Commercial Fulfillment Snapshot

Buy Sodium Bisulfite 40% ACS Grade with faster decisions and fewer back-and-forth emails.

Ships from Taylor, Texas. In-stock orders placed before 1:00 PM CT (Mon-Thu) and before 12:00 PM CT (Fri) typically ship within 1-2 business days. Order online 24/7.

Technical Documents

Lot-specific COA is issued per shipment batch.

Who Buys This
  • Analytical testing laboratories
  • Research & development facilities
  • QA/QC departments
  • Pharmaceutical manufacturers
  • Chemical synthesis operations
Purity / Grade Guide
  • ACS reagent grade purity
  • Analytical chemistry applications
  • Pharmaceutical & research use
  • 40% concentration verified by COA specification
Pack Sizes
  • 1 Quart: lab & small jobs
  • 1 Gallon: shop & maintenance
  • 5 Gallon: production & regular use
  • 15 Gallon: mid-volume operations
  • 55 Gallon: bulk drum
  • 275 Gallon: high-volume tote
  • 330 Gallon: max-volume tote
SDS / COA / TDS
  • UN 2693 Class 8 shipping
  • Safety data sheet included
  • Certificate of analysis provided
  • ACS specification compliance
Small Packs: UPS Ground nationwide for pints, quarts, and gallons.
LTL / FTL: ABF, SEFL, Saia, XPO, and partner carriers for pails, drums, totes, and full truckloads.
Support: Email or call for freight options, hazardous-material routing, and lead-time confirmation.

Product Overview

Sodium Bisulfite 40% ACS Grade is a high-purity aqueous solution of sodium hydrogen sulfite (CAS 7631-90-5) — formulated to meet the stringent specifications established by the American Chemical Society. This chemical, represented by the molecular formula HNaO3S and a molecular weight of 104.06, functions primarily as a powerful reducing agent and dechlorination agent across various specialized industrial systems. Alliance Chemical distributes this precise 40% liquid formulation to ensure immediate utility in processing environments, removing the need for onsite dissolution of dry powder and minimizing associated dust inhalation hazards.

Our ACS Grade liquid formulation exhibits a clear to pale yellow appearance and carries a slight sulfurous odor, reflecting its active bisulfite content. With a typical pH range of 2.5–5.5 for a 10% aqueous solution, this product delivers consistent performance in chemical synthesis, redox chemistry, and photographic processing. As a trusted Texas chemical supplier, we manage rigorous quality controls to maintain the stability of this solution, preventing rapid decomposition and ensuring the assay remains at the stated concentration throughout its shelf life. We supply this solution in multiple packaging sizes to suit both laboratory and large-scale industrial requirements.

Why This Grade

Selecting ACS Grade sodium bisulfite at a 40% concentration is critical for applications where trace metallic impurities can interfere with sensitive chemical reactions or analytical procedures. The American Chemical Society standard guarantees exceptionally low limits for heavy metals, iron, and other potential contaminants. Utilizing a lower technical grade in analytical testing or high-precision manufacturing can introduce unwanted ions that poison catalysts, alter reaction kinetics, or cause precipitation in delicate equipment. For facilities managing high-throughput processes, using a verified 40% concentration ensures reliable stoichiometry without the variability associated with mixing dry crystalline sodium bisulfite on the factory floor.

A major failure mode in systems using substandard grades is the presence of excess sulfates or heavy metal residues, which can lead to unwanted side reactions and product discoloration. In water treatment and industrial bleaching operations, these impurities can degrade the efficiency of the dechlorination process, leading to equipment corrosion or failure to meet strict compliance parameters. By choosing this high-purity ACS solution, process engineers avoid the risks of inconsistent concentration drifts and particulate contamination. Alliance Chemical provides this premium grade to help maintain the integrity of your process, preventing costly downtime and batch contamination that often results from utilizing lower-tier industrial reagents.

Chemical Profile

CAS Number
7631-90-5
Chemical Formula
HNaO3S
Molecular Weight
104.06 g/mol
Boiling Point
Decomposes (NIOSH, 2024) °C
Melting Point
Decomposes (NIOSH, 2024) °C
Flash Point
Non-flammable °C
Specific Gravity
1.48 at 68 °F (USCG, 1999) - Denser than water; will sink
Appearance
Sodium bisulfite appears as white crystals or crystalline powder. Slight sulfurous odor. Specific gravity 1.48. Strong irritant to skin and tissue.
Solubility
29 % (NIOSH, 2024)
UN Number
UN2693
Hazard Class
Class 8
Packing Group
III
Proper Shipping Name
Bisulfites, aqueous solutions, n.o.s. (Sodium bisulfite)
GHS Signal Word
Danger

Values sourced from Alliance Chemical's canonical chemistry registry. Certificate of Analysis (COA) per lot.

Industrial Applications

  • Chlorine Removal in Wastewater: Used in commercial municipal systems to neutralize residual chlorine in industrial wastewater before environmental discharge, protecting downstream ecosystems from toxic halogen exposures.
  • Textile Bleaching and Dyeing: Serves as a critical reducing agent in the textile industry to remove excess chlorine after bleaching processes and to maintain dye bath consistency.
  • Paper and Pulp Processing: Utilized in the bleaching of wood pulp, aiding in the reduction of residual lignin and neutralizing residual peroxide compounds during paper manufacturing.
  • Laboratory Synthesis and Reagent Prep: Functions as a key reducing agent in organic synthesis pathways, helping to reduce carbonyl groups, alkenes, and other sensitive functional groups in controlled environments.
  • Leather Tanning and Processing: Applied in the de-liming stage of leather manufacturing to neutralize alkaline residues and prepare hides for subsequent chrome or vegetable tanning procedures.

Hazmat & Shipping

Sodium Bisulfite 40% ACS Grade is classified as a hazardous material for transport. It is regulated under United States Department of Transportation (DOT) guidelines as UN2693, hazard class 8 (Corrosive), packing group III. The proper shipping name is strictly designated as Bisulfites, aqueous solutions, n.o.s. (Sodium bisulfite). The designated signal word for this chemical is Danger. Because of its corrosive nature and chemical properties, this liquid must be shipped in specialized, corrosion-resistant packaging and handled by certified hazmat carriers. Alliance Chemical coordinates all logistics in strict compliance with federal and state regulations, ensuring safe transit to your facility.

Under the Globally Harmonized System (GHS), this compound is associated with hazard statement H302 (Harmful if swallowed). In accordance with the precautionary statements P264, P270, P301+P317, P330, and P501, personnel must wear appropriate personal protective equipment (PPE) during handling. This includes chemical-resistant safety goggles, heavy-duty nitrile or neoprene gloves, and protective clothing to prevent direct skin contact or ingestion risks. A Safety Data Sheet (SDS) is provided with every order to detail exact exposure thresholds, spill mitigation protocols, and safe handling guidelines. Proper ventilation must be maintained in all work areas to prevent the accumulation of sulfur dioxide gas, which can desorb from the liquid under acidic conditions.

Handling & Storage

Proper storage of Sodium Bisulfite 40% ACS Grade requires maintaining a temperature range between 50°F and 85°F (10°C to 29°C) to prevent crystallization or accelerated decomposition. Store this chemical in original, tightly sealed containers made of compatible materials such as high-density polyethylene (HDPE), polypropylene, or glass. Avoid contact with incompatible materials, including strong oxidizers, mineral acids, and metals such as copper, brass, and mild steel, as contact can liberate toxic sulfur dioxide gas or cause rapid container degradation. For safety compliance, ensure storage areas are equipped with secondary containment and proper ventilation.

Order & Documentation

Alliance Chemical simplifies the procurement process for your chemical inventory in our salts collection. Our high-purity sodium bisulfite solution is available in various quantities from quarts to bulk gallons, perfect for laboratory analysis or manufacturing scales. A Certificate of Analysis (COA) is available upon request for every batch we ship, verifying critical purity standards. For purchasing questions or to secure volume pricing, please Request a Quote or Download the SDS for your safety records.

Why Buy from Alliance Chemical

Since 1997, Alliance Chemical has supplied premium industrial chemicals from Taylor, Texas under CAGE Code 1LT50, with a COA and SDS included on every order. For industrial use only.

Property Value
Molecular Weight 104.06
Formula NaHSO3
Assay 39-41%
Grade ACS Grade
Flash Point Non-flammable
Form Liquid
Solubility Soluble in water
Appearance Colorless to pale yellow liquid
Melting Point -10°C
Boiling Point 103°C
Specific Gravity 1.2
Industry Environmental, Analytical Chemistry, Food Industry, Photographic Industry, Chemical Manufacturing

Frequently Asked Questions About Sodium Bisulfite 40% ACS Grade

What is Sodium Bisulfite 40% ACS Grade and what is its chemical formula?
Sodium Bisulfite 40% ACS Grade is a chemical compound with the molecular formula HNaO3S, registered under CAS Number 7631-90-5 by the Chemical Abstracts Service (PubChem), with a molecular weight of 104.06 g/mol. Alliance Chemical supplies Sodium Bisulfite 40% ACS Grade in ACS Reagent grade for laboratory, industrial, and commercial applications.
What are the physical properties of Sodium Bisulfite 40% ACS Grade?
According to the NIOSH Pocket Guide to Chemical Hazards, Sodium Bisulfite 40% ACS Grade is supplied as a clear to pale yellow liquid. It has a melting point of '-10°C°C, a boiling point of 103°C°C, a flash point of Non-flammable. The specific gravity is 1.36 relative to water. Solubility: Highly soluble in water, moderate alcohol soluble.
What grade and purity of Sodium Bisulfite 40% ACS Grade does Alliance Chemical offer?
Alliance Chemical offers Sodium Bisulfite 40% ACS Grade in ACS Reagent grade with a purity assay of 40%. Every lot ships with a Certificate of Analysis (COA) and Safety Data Sheet (SDS) prepared in accordance with OSHA Hazard Communication Standard 29 CFR 1910.1200 and GHS Revision 7. Download SDS.
What are common industrial applications of Sodium Bisulfite 40% ACS Grade?
Sodium Bisulfite 40% ACS Grade serves a wide range of sectors, including Industrial & Manufacturing, and Water & Environmental.Alliance Chemical provides the documentation and quality certifications required for use in regulated environments.
What PPE is required when handling Sodium Bisulfite 40% ACS Grade?
OSHA-mandated PPE per 29 CFR 1910.132-138:Nitrile gloves (8+ mil), safety goggles, flame-resistant clothing, grounded footwear, closed-toe chemical-resistant footwear. Respiratory protection (organic vapor cartridge) required in areas exceeding PEL/TLV per 29 CFR 1910.134. Emergency eyewash station and safety shower must be accessible within 10 seconds per ANSI Z358.1. Consult the SDS available from Alliance Chemical for complete PPE requirements.
What are the storage requirements for Sodium Bisulfite 40% ACS Grade?
Store perOSHA 29 CFR 1910.106: Approved flammable storage cabinet, maximum 60 gallons per cabinet, grounding/bonding required. Temperature range:15-25°C. Segregate from:oxidizers, ignition sources. Maximum storage:2-3 years unopened.
What is the emergency spill procedure for Sodium Bisulfite 40% ACS Grade?
Emergency response per EPA SPCC (40 CFR 112) and OSHA 29 CFR 1910.120: (1) Alert personnel, evacuate area to 100 feet. (2) Eliminate ignition sources if flammable. (3) Don PPE per SDS Section 8. (4) Stop leak if safe; use emergency shutoffs. (5) Contain with non-combustible absorbent materials, dike with sand/earth. (6)Absorb with vermiculite or commercial spill kits. (7) Collect in DOT-approved containers, label as hazardous waste. Check 40 CFR 302.4 for Reportable Quantity. Emergency: Chemtel 1-800-255-3924 (24/7). Non-emergency: Alliance Chemical 512-365-6838.
What is the DOT shipping classification for Sodium Bisulfite 40% ACS Grade?
DOT Classification per 49 CFR 172.101:UNUN2693, Hazard Class8, Packing GroupIII. Requires: Hazmat shipping papers (49 CFR 172.200), UN specification packaging (49 CFR 173), hazmat labels (172.400). Alliance Chemical ships all orders in DOT-compliant packaging with proper documentation.
How must Sodium Bisulfite 40% ACS Grade waste be disposed?
Disposal per RCRA (40 CFR 261-265):Characteristic waste D001 (Ignitable, flash point <60°C). Generator requirements: EPA ID number required if >100 kg/month (40 CFR 262.12). Use EPA-permitted Treatment, Storage, Disposal Facility (TSDF). Never discharge to sewer without POTW written approval (40 CFR 403). Container disposal: Triple rinse (40 CFR 261.7), offer for reconditioning/recycling. State regulations may be more stringent — check with your local environmental agency. Consult the Alliance Chemical SDS for product-specific disposal guidance.
Does Alliance Chemical provide an SDS and COA for Sodium Bisulfite 40% ACS Grade?
Yes. Alliance Chemical provides a Safety Data Sheet (SDS) and Certificate of Analysis (COA) for every lot of Sodium Bisulfite 40% ACS Grade. The SDS is prepared in accordance with OSHA Hazard Communication Standard 29 CFR 1910.1200 and the Globally Harmonized System (GHS) Revision 7, covering all 16 required sections including hazard identification, first aid measures, firefighting measures, handling and storage, exposure controls, and regulatory information. The SDS is available for download directly from this product page. COAs are available upon request by contacting Alliance Chemical at 512-365-6838.