D-Limonene Technical Grade

CAS
5989-27-5
Formula
C10H16
UN number
UN2319
$59.00
$59.00

1 Quart Can

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1 Quart Can About 7 inches tall

Size comparison to scale. Heights are approximate.

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Ships UPS Ground
Quantity
In Stock — ready to ship from our Taylor, TX warehouse Order by Mon-Thu 2 PM CT / Fri 12 PM CT — ships in 1–2 business days If it’s listed, it’s on our shelf. No backorders, no 4-week lead times. Why
Temporarily unavailable This item isn’t ready to ship right now. Call 512-365-6838 for restock timing.
  • No hazmat fees from us — you pay the carrier’s shipping rate, at cost
  • Gallon+ sizes usually ship as fully regulated hazmat (small sizes often go as Limited Quantity), so carrier freight runs higher — how shipping works
  • Drums, totes & pails ship LTL freight — liftgate delivery available
  • PO / Net 30 for approved businesses · tax-exempt ordering supported

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CAS: 5989-27-5 C10H16

D-Limonene Technical Grade

$59.00
Ball-and-stick model of D-Limonene

D-Limonene

Technical grade D-Limonene delivers full industrial solvency at a lower cost than food or fragrance grades — suited for degreasing, cleaning, coatings formulation, and extraction work where high analytical purity is not required.

Also known as
(4R)-1-methyl-4-prop-1-en-2-ylcyclohexene · (R)-(+)-limonene · (+)-limonene
CAS number
5989-27-5
Formula
C10H16
Molecular weight
136.23 g/mol
Concentration
100%
Grade
Technical Grade
Appearance
Clear to pale yellow liquid, citrus-like odor
Flash point
119 °F
Boiling point
348 to 349 °F at 760 mmHg

How it is classified for shipping

UN number
UN2319
Hazard class
3 Flammable liquid
Packing group
III

Proper shipping name Terpene hydrocarbons, N.O.S.

Hazards

Signal word Danger

  • Flammable
  • Irritant
  • Health hazard
  • Environmental hazard

Summary only. Read the SDS and the container label for complete hazard and handling information.

SDS also in

Who uses it

Maintenance supervisors and shop foremen sourcing a citrus-based degreaser for parts washing, coatings formulators replacing petroleum solvents, and extraction operators working with plant-derived materials.

  • Capped glass sample vials in a numbered tray inside a laboratory instrument
    Laboratory & Pharmaceutical
  • Stainless-steel process tanks and sanitary piping on a steel platform in an industrial plant
    Manufacturing & Industrial

Representative industry photos.

Product quick facts

CAS 5989-27-5C10H16UN2319

D-Limonene Technical Grade (CAS 5989-27-5) is a 100% Technical Grade liquid with molecular formula C10H16 and a molecular weight of 136.23 g/mol, for industrial and manufacturing applications. It is also known as (4R)-1-methyl-4-prop-1-en-2-ylcyclohexene, (R)-(+)-limonene and (+)-limonene. It has a flash point of 119 °F, classifying it as a NFPA Class II combustible liquid, and it ships as DOT Hazard Class 3. Alliance Chemical supplies this product in 5 container sizes from 1 Quart to 55 Gallon (15 pack options) with 1-2 business day shipping from Taylor, TX on in-stock orders, plus SDS and lot-specific Certificate of Analysis.

  • Pack sizes 5 container sizes (1 Quart to 55 Gallon) · 15 pack options
  • Purity / spec 100% Technical Grade
  • Lead time In-stock orders placed by Mon-Thu 2 PM CT / Fri 12 PM CT typically ship within 1-2 business days.
  • Regional availability View state-by-state shipping pages
Forklift moving pallets in a warehouse

Stock footage.

How it ships.

Regulated products are packed, marked, and labeled for hazmat transport, from one quart to a pallet of drums.

  • Most stocked orders ship in 1–2 business daysOrder cutoff: Mon-Thu 2 PM CT / Fri 12 PM CT
  • Hazmat packing, marking, and labelingPacked by staff trained under DOT rule 49 CFR 172.704
  • UPS Ground for bottles, jugs, and up to three pailsLTL freight for four or more pails, drums, and totes. Liftgate on request.
  • Ships with
  • UPS
  • FedEx Freight
  • ABF Freight
  • R+L Carriers
  • Saia
  • Southeastern Freight Lines
  • XPO

Buying for a company or agency?

Pay by card at the listed price, or order on Net 30 terms once your credit is approved. For NSN and contract requirements, send an RFQ.

CAGE code
1LT50
UEI
DCTCZDY3BLD3
Primary NAICS
424690
Ownership
Woman-Owned
Federal supply
DLA Supplier
Terms
Net 30 on approved credit, W-9 on request
Gloved hands strapping four blue chemical drums to a pallet at a warehouse loading dock
Illustration.

Safety data sheets and certificates.

Find an SDS or TDS by product name or CAS number. Certificates of analysis are free on request.

Find an SDS or COA

Selected organizations we've supplied

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Product Overview

D-Limonene Technical Grade is a naturally derived terpene solvent with strong solvency for oils, greases, adhesives, and resins. It is a clear, colorless, mobile liquid with a distinct citrus odor — immediately recognizable when you crack the cap on a fresh drum. As a technical grade product, it is formulated for industrial process work where high analytical purity is unnecessary but reliable solvent performance is expected.

This product moves through our Taylor, TX warehouse steadily. Buyers are typically maintenance supervisors sourcing a parts-washing solvent, coatings formulators replacing petroleum-based solvents, or extraction operators working with plant-derived materials. If your process calls for a terpene hydrocarbon solvent that dissolves non-polar residues without the toxicity profile of chlorinated alternatives, this is the product.

Why This Grade

Technical grade D-Limonene is the workhorse tier. It delivers the solvency and evaporation profile you need for cleaning, degreasing, and formulation work at a lower cost point than food or fragrance grades. The trade-off is straightforward: technical grade carries minor impurities that do not affect performance in industrial solvent applications but would matter in flavor, fragrance, or pharmaceutical contexts.

Choose technical grade when your end product is not consumed, inhaled at close range, or applied to skin — that covers parts washing, ink removal, adhesive stripping, concrete degreasing, paint thinning, and most extraction work. If your application requires tighter purity specifications, request a COA for this lot and compare against your process tolerances.

Chemical Profile

D-Limonene (CAS 5989-27-5) has the molecular formula C10H16 and a molecular weight of 136.23. It is a liquid at room temperature — clear, colorless, and mobile, with a pleasant citrus odor. Its density is 0.8411 at 68 °F, making it less dense than water; it will float on an aqueous layer. Solubility in water is very low, less than 1 mg/mL at 67.1 °F, so it behaves as a distinct organic phase in aqueous systems. Vapor pressure is 1 mmHg at 57 °F, rising to 5 mmHg at 104.7 °F and 10 mmHg at 128.8 °F — moderate volatility that provides good evaporation in cleaning applications without the flash-off speed of lighter solvents like acetone.

Industrial Applications

D-Limonene's value is its ability to dissolve a wide range of non-polar substances while offering a more favorable health and environmental profile than many petroleum solvents. Here are the primary industrial uses:

  • Degreasing and Parts Cleaning — D-Limonene cuts through petroleum greases, lubricants, and machining oils on metal parts. It is used in dip tanks, spray washers, and manual wipe-down operations. Because it evaporates cleanly and leaves minimal residue, it works well for pre-painting or pre-coating surface preparation.
  • Solvent for Paints and Coatings — Formulators use D-Limonene as a solvent or co-solvent in coatings, varnishes, and ink systems. It dissolves many resins effectively and can replace mineral spirits or toluene in formulations where a lower-toxicity solvent is preferred.
  • Cleaning Products — Industrial and institutional cleaning formulations use D-Limonene to dissolve oils, waxes, and adhesive residues from hard surfaces. Its citrus odor is a practical advantage in occupied facilities where solvent odor is a concern.
  • Extraction Solvent — D-Limonene serves as a solvent for extracting essential oils and active compounds from plant materials. Its selectivity for terpenes and other non-polar compounds makes it effective in botanical extraction processes.
  • Chemical Intermediate — D-Limonene is a feedstock for synthesizing other terpene derivatives. It serves as a starting material in chemical manufacturing processes that produce downstream specialty chemicals.
  • Fragrance and Aroma Applications — At technical grade, D-Limonene is incorporated into industrial fragrance blends, air freshener formulations, and odor-masking products where its citrus character is the functional ingredient.

Handling & Storage

D-Limonene carries a signal word of Danger (per the product's GHS classification). The hazard statements you need to know: it is a flammable liquid and vapor (H226), may be fatal if swallowed and enters airways (H304), causes skin irritation (H315), may cause an allergic skin reaction (H317), and is very toxic to aquatic life with long-lasting effects (H410) (per the product's GHS classification).

Wear chemical-resistant gloves (nitrile recommended) and splash-proof safety goggles when handling. In poorly ventilated areas or during prolonged exposure, use respiratory protection rated for organic vapors. Avoid skin contact — repeated exposure can cause sensitization in some individuals.

Store in a cool, dry, well-ventilated area away from direct sunlight, heat sources, and open flame. Keep containers tightly closed when not in use. Use HDPE or glass containers; D-Limonene can soften or degrade some plastics and rubber seals over time. Keep away from strong oxidizing agents. Do not allow releases to drains, waterways, or soil — the aquatic toxicity profile demands spill containment and proper disposal.

Hazmat & Shipping

D-Limonene ships as a regulated hazardous material. Every outbound shipment from our Taylor, TX facility is packaged and labeled to DOT standards:

  • UN Number: UN2319 (per 49 CFR 172.101)
  • Hazard Class: 3 — Flammable Liquid (per 49 CFR 172.101)
  • Packing Group: III (per 49 CFR 172.101)
  • Proper Shipping Name: Terpene hydrocarbons, N.O.S. (per 49 CFR 172.101)

Packing Group III means this is the lowest-severity tier within Class 3 flammable liquids, but it still requires full hazmat documentation, diamond placarding on bulk shipments, and compliant packaging at every size. We handle that end to end — you receive a properly marked, labeled, and documented package.

Documentation

A Safety Data Sheet ships with every order, available in English, Spanish, French, and Japanese. A lot-specific Certificate of Analysis is available on request — contact us before or after your order to obtain the COA matched to your shipment lot. A Technical Data Sheet is also available for process engineering reference.

Why Buy from Alliance Chemical

We ship D-Limonene daily from our warehouse in Taylor, TX. Every hazmat package is built, marked, and documented by our operations team under the review of Andre Taki, DOT Hazmat Specialist. We are a chemical distributor — stocking, handling, and shipping hazardous materials is what we do, and we do it every day. From a single quart for bench testing to a 55-gallon drum for production, your order ships DOT-compliant with full documentation. No third-party drop shipping. No guesswork on hazmat compliance. Alliance Chemical does not charge hazmat handling fees.

Related Reading

The 2026 chemistry Nobel (Kagan and Soai, 7 October 2026) rewarded reactions that make one mirror image of a molecule. The D in D-limonene is a mirror-image label: citrus makes (R)-limonene above 99.9 percent ee. A 2021 J. Chem. Educ. study found half of testers called technical-grade (R)-limonene orange but only 13 percent said so of analytical grade: the orange note rides on the impurities. The Chemistry Nobel Went to Mirror Molecules. Textbooks Still Get Limonene Wrong.

Frequently Asked Questions About D-Limonene Technical Grade

What is D-Limonene Technical Grade used for?
It is primarily used as an industrial solvent and degreaser. It effectively removes oil, grease, tar, asphalt, and adhesives from metal surfaces, concrete, and equipment. It is also used in paint formulations and chemical synthesis.
Is this D-Limonene suitable for food or flavoring?
No. This is Technical Grade D-Limonene intended for industrial use only. It does not meet Food Chemical Codex (FCC) standards and should not be used for food, beverages, or ingestion.
Is D-Limonene soluble in water?
No, D-Limonene is insoluble in water. It is soluble in alcohol and other hydrocarbon solvents, making it ideal for solvent-based cleaning applications.
What is D-Limonene Technical Grade and what is its chemical formula?
D-Limonene Technical Grade is listed under CAS 5989-27-5 (PubChem reference search). The catalog formula is C10H16. The listed molecular weight is 136.23 g/mol. For solutions and blends, identity values may describe a constituent; consult the product SDS for composition.
What are the physical properties of D-Limonene Technical Grade?
Catalog reference information for D-Limonene Technical Grade: form: Liquid; appearance: Clear to pale yellow liquid, citrus-like odor; melting point: -142.4 °F; boiling point: 348 to 349 °F at 760 mmHg; flash point: 119 °F; solubility: Insoluble in water, soluble in organics; reference values may describe a pure substance rather than the supplied concentration or blend. Confirm applicable conditions and specifications in the product documents; these values are not batch test results.
What grade and purity of D-Limonene Technical Grade does Alliance Chemical offer?
Alliance Chemical lists D-Limonene Technical Grade in Technical Grade with a concentration or assay of 100%. Check the product specification for the measurement basis and acceptance limits. A grade label alone does not establish certification or suitability for a regulated application. For batch results, request a COA using the product name and lot number.
What are common industrial applications of D-Limonene Technical Grade?
Catalog industry categories for D-Limonene Technical Grade include Laboratory & Pharmaceutical, Manufacturing & Industrial. To evaluate it for your process, compare the listed grade, concentration and product specifications with your requirements. Contact Alliance Chemical to confirm any application-specific documentation or certification before ordering.
What are the hazards of D-Limonene Technical Grade and where do I find handling guidance?
Per its GHS classification (SDS Section 2), D-Limonene Technical Grade carries the signal word Danger and the following hazard statements: H226 (Flammable liquid and vapour); H304 (May be fatal if swallowed and enters airways); H315 (Causes skin irritation); H317 (May cause an allergic skin reaction); H410 (Very toxic to aquatic life with long lasting effects). Product-specific first aid, fire-fighting, spill response, handling, storage, exposure controls/PPE, and disposal guidance are in SDS Sections 4-8 and 13 — always consult the SDS before use. Download the SDS.
What is the DOT shipping classification for D-Limonene Technical Grade?
The catalog transport entry lists UN2319, hazard class 3, packing group III. Consult SDS Section 14 and confirm the requirements for your selected pack size and shipping destination with Alliance Chemical.
How must D-Limonene Technical Grade waste be disposed?
Consult SDS Section 13 for disposal information for D-Limonene Technical Grade. Disposal requirements depend on the resulting waste, contamination and location. Have your site's responsible waste professional determine the appropriate waste classification and disposal method. View the SDS.
Does Alliance Chemical provide an SDS and COA for D-Limonene Technical Grade?
Search the document library for D-Limonene Technical Grade. The SDS is also available here. A sample COA describes specifications and does not establish the results for your shipment. To request a lot-specific COA or confirm document availability, contact Alliance Chemical with the product name and lot number.