Phosphoric Acids

H3PO4 30% to 85% — ACS, USP & food grade

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Phosphoric Acid 85% USP Food Grade

85%USP Food Grade

Available sizes: 1 Quart–250 Gallon

From $42.90
Phosphoric Acid 85% - Technical Grade

85%Technical Grade

Available sizes: 1 Quart–330 Gallon

From $42.90
Phosphoric Acid 75% USP Food Grade

75%USP Food Grade

Available sizes: 1 Quart–330 Gallon

From $19.80
Phosphoric Acid 75% Technical Grade

75%Technical Grade

Available sizes: 1 Quart–330 Gallon

From $19.80
Phosphoric Acid 30% - The Ultimate Rust Remover...

30%Technical Grade

Available sizes: 1 Quart–330 Gallon

From $20.20
Phosphoric Acid 85% ACS Grade

85%ACS Reagent Grade

Available sizes: 1 Quart–330 Gallon

From $31.60
Phosphoric Acid 5% Food Grade

5%Food Grade

Available sizes: 1 Quart–330 Gallon

From $20.75
Phosphoric Acid 50% ACS Grade

50%ACS Reagent Grade

Available sizes: 1 Quart–330 Gallon

From $23.50
Phosphoric Acid 20% ACS Grade

20%ACS Reagent Grade

Available sizes: 1 Quart–330 Gallon

From $22.20
Phosphoric Acid 45% Technical Grade

45%Technical Grade

Available sizes: 1 Quart–330 Gallon

From $20.80
pH-Ree Fall - World Class Buffering Solution For...

30%Technical Grade

Available sizes: 1 Quart–330 Gallon

From $22.05
Phosphoric Acid 50% Food Grade

50%Food Grade

Available sizes: 1 Quart–330 Gallon

From $22.70
Phosphoric Acid 10% Food Grade

10%Food Grade

Available sizes: 1 Quart–330 Gallon

From $20.95
Phosphoric Acid 50% Technical Grade

50%Technical Grade

Available sizes: 1 Quart–330 Gallon

From $21.00
Phosphoric Acid 75 ACS Grade

75%ACS Reagent Grade

Available sizes: 1 Quart–330 Gallon

From $31.60
Phosphoric Acid 45% ACS Grade

45%ACS Reagent Grade

Available sizes: 1 Quart–330 Gallon

From $23.30

About Phosphoric Acids

Alliance Chemical is a bulk phosphoric acid supplier stocking H₃PO₄ (CAS 7664-38-2) from 5% to 85% in four grades — USP Food Grade, Food Grade, Technical Grade, and ACS Reagent Grade — packaged from single quarts to 55-gallon drums and 275- and 330-gallon IBC totes. A 55-gallon drum of 75% starts at $1,525, every order ships from our warehouse in Taylor, Texas with no hazmat fee and no minimum order, and most in-stock orders leave in 1–2 business days.

Choose a grade

The grade on each product page is the grade in the certificate, stated per SKU and never inferred. Concentration and grade are separate choices — most strengths from 5% to 85% are stocked in more than one grade, so pick the grade your specification requires first, then the strength your process wants.

Grade What picks it
USP Food Grade (75%, 85%) Meets the USP/FCC monograph — the specification beverage, food-processing, and dietary-supplement buyers require for acidulation and pH control
Food Grade (5%–50%) Pre-diluted working strengths of food-specification acid for process lines that dose below concentrate strength
Technical Grade (5%–85%) The industrial tier for metal prep and rust removal, water treatment, fertilizer chemistry, and general process work — including the 30% rust remover blended for direct use
ACS Reagent Grade (5%–85%) Certified to ACS specifications for procedures that name a reagent-grade acid

Why 75% exists — and when to buy it over 85%

85% phosphoric acid is the standard commercial concentrate, but it begins to crystallize around 70 °F — a drum stored in an unheated warehouse or shipped in winter can arrive partly solid. 75% stays liquid far below freezing, which is why cold-climate plants and winter buyers specify it — and it is cheaper per drum. If your process is water-sensitive and needs maximum P₂O₅ per gallon, take 85% and store it warm; if handling temperature is outside your control, 75% is the practical choice.

Drum and tote pricing

These are the live single-container prices as of 2026-08-17 — the same prices in the cart, with per-gallon economics at the volume breaks. A 55-gallon drum of 85% Technical Grade is $1,803 ($32.78/gal). The 5%–50% dilutions in every grade are priced on their product pages; standing-order volume is quoted at 512-365-6838.

Product 1 Gallon 5 Gallon 55-Gal Drum 275-Gal Tote
85% USP Food Grade $87 $303 $1,980 ($36.00/gal) (—)
85% Technical Grade $83 $285 $1,803 ($32.78/gal) $8,910 ($32.40/gal)
85% ACS Reagent Grade $84 $294 $2,541 ($46.20/gal) $11,069 ($40.25/gal)
75% USP Food Grade $45 $166 $1,525 ($27.73/gal) $6,019 ($21.89/gal)
75% Technical Grade $45 $166 $1,525 ($27.73/gal) $6,019 ($21.89/gal)
30% Rust Remover — Technical Grade $49 $186 $1,628 ($29.60/gal) $6,764 ($24.60/gal)

How phosphoric acid ships

Phosphoric acid solution is a DOT-regulated corrosive: UN1805, Phosphoric acid solution, Hazard Class 8. Quarts and gallons ship by ground parcel; drums and totes move as LTL corrosive-class freight from Taylor, Texas on our regular carriers. Alliance Chemical does not add a hazmat fee at any package size — the price on the page is the price. Most in-stock orders ship within 1–2 business days.

COA and SDS

A lot-specific Certificate of Analysis — for the lot you receive, not a generic sample — is available for every product in this collection through the COA request page. Safety Data Sheets for every grade are in the SDS library; review the SDS before handling. Phosphoric acid is corrosive to skin and eyes and attacks ordinary steel — use compatible materials (316 stainless, HDPE, PVC) for storage and transfer.

Common applications

  • Rust removal and metal prep: phosphoric acid converts red iron oxide to a stable phosphate layer — the chemistry behind rust converters and pre-paint metal treatment.
  • Food and beverage acidulation: USP Food Grade acid provides tartness and pH control in beverages and processed foods, and cleans food-contact process equipment.
  • Water treatment: corrosion-control dosing and pH adjustment in municipal and industrial systems.
  • Fertilizer and chemical feedstock: the phosphorus source for phosphate salt production and agricultural formulation.

Why Buy From Alliance Chemical

Alliance Chemical is a wholesale phosphoric acid distributor shipping from Taylor, Texas. Single quarts and full tote quantities get the same treatment: lot-specific COA support, current SDS on every product, volume pricing printed on the page rather than hidden behind a quote form, and no hazmat fees.

Related: Sulfuric Acid, Hydrochloric Acid, Food-Grade Phosphoric Acid Guide.

Frequently Asked Questions

What is phosphoric acid used for?
Phosphoric acid is used for rust conversion, metal treatment, food and beverage acidulation, pH adjustment, cleaning, descaling, and industrial process chemistry.
What is the difference between food grade and technical grade phosphoric acid?
Food or USP grades are selected when a regulated food, beverage, or formulation process requires that specification. Technical grade is used for industrial cleaning, pH control, and metal treatment where food-grade documentation is not required.
Can phosphoric acid remove rust?
Yes. Phosphoric acid can convert iron oxide and support rust-removal workflows on compatible metal surfaces when concentration, contact time, and rinsing are controlled.
Is phosphoric acid an oxidizing acid?
Phosphoric acid is generally considered a non-oxidizing mineral acid, unlike nitric acid. It is still corrosive and requires acid-rated handling controls.
Does phosphoric acid require hazmat shipping?
Shipping requirements depend on concentration, package size, destination, and transport mode. Review the product SDS and order details for the applicable classification.