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Phosphoric Acids

H3PO4 5% to 85% — Technical, ACS, Food & USP Food grades

Buy phosphoric acids online: 27 products, 1 Quart to 330 Gallon. Ships from Texas in 1–2 business days with the SDS on every product page. From $10.00.

Products
27
Sizes
1 Quart to 330 Gallon

Which phosphoric acids grade do I need?

Every grade we stock, with the size range and the starting price. Prices are per container and update with the catalog.

ProductStrengthGradeSizesFromBuy
Phosphoric Acid 85% USP Food Grade85%USP Food Grade1 Quart to 330 Gallon$21.00Buy
Phosphoric Acid 85% Technical Grade85%Technical Grade1 Quart to 330 Gallon$20.00Buy
Phosphoric Acid 75% USP Food Grade75%USP Food Grade1 Quart to 330 Gallon$19.80Buy
Phosphoric Acid 75% Technical Grade75%Technical Grade1 Quart to 330 Gallon$19.00Buy
Phosphoric Acid 30% - The Ultimate Rust Remover Solution Technical Grade30%Technical Grade1 Quart to 330 Gallon$20.20Buy
Phosphoric Acid 85% ACS Grade85%ACS Reagent Grade1 Quart to 330 Gallon$25.50Buy
Phosphoric Acid 5% Food Grade5%Food Grade1 Quart to 330 Gallon$10.50Buy
Phosphoric Acid 10% Food Grade10%Food Grade1 Quart to 330 Gallon$11.50Buy
Phosphoric Acid 45% Technical Grade45%Technical Grade1 Quart to 330 Gallon$15.00Buy
Phosphoric Acid 50% ACS Grade50%ACS Reagent Grade1 Quart to 330 Gallon$20.00Buy
Phosphoric Acid 20% ACS Grade20%ACS Reagent Grade1 Quart to 330 Gallon$15.00Buy
pH-Ree Fall - World Class Buffering Solution For PH Stability Made From Phosphoric Acid Technical Grade30%Technical Grade1 Quart to 330 Gallon$22.05Buy
Phosphoric Acid 50% Food Grade50%Food Grade1 Quart to 330 Gallon$16.50Buy
Phosphoric Acid 50% Technical Grade50%Technical Grade1 Quart to 330 Gallon$15.50Buy
Phosphoric Acid 15% Technical Grade15%Technical Grade1 Quart to 330 Gallon$11.50Buy
Phosphoric Acid 5% Technical Grade5%Technical Grade1 Quart to 330 Gallon$10.00Buy
Phosphoric Acid 75% ACS Grade75%ACS Reagent Grade1 Quart to 330 Gallon$24.00Buy
Phosphoric Acid 30% ACS GradeACS Reagent Grade1 Quart to 330 Gallon$17.00Buy
Phosphoric Acid 45% ACS Grade45%ACS Reagent Grade1 Quart to 330 Gallon$19.00Buy
Phosphoric Acid 5% ACS Grade5%ACS Reagent Grade1 Quart to 330 Gallon$13.00Buy
Phosphoric Acid 45% Food Grade45%Food Grade1 Quart to 330 Gallon$16.00Buy
Phosphoric Acid 20% Food Grade20%Food Grade1 Quart to 330 Gallon$12.50Buy
Phosphoric Acid 20% Technical Grade20%Technical Grade1 Quart to 330 Gallon$12.00Buy
Phosphoric Acid 15% ACS Grade15%ACS Reagent Grade1 Quart to 330 Gallon$14.50Buy
Phosphoric Acid 10% ACS Grade10%ACS Reagent Grade1 Quart to 330 Gallon$13.50Buy
Phosphoric Acid 15% Food Grade15%Food Grade1 Quart to 330 Gallon$12.00Buy
Phosphoric Acid 10% Technical Grade10%Technical Grade1 Quart to 330 Gallon$11.00Buy

27 products

Phosphoric Acids products

About Phosphoric Acids

Start with your specification

Choose the required grade first, then concentration and container size. For application context, read our phosphoric acid grades and uses guide. For metal preparation, see the rust-removal guide and verify compatibility with your process.

Alliance Chemical is a bulk phosphoric acid supplier stocking H₃PO₄ (CAS 7664-38-2) from 5% to 85% in four grades — USP Food Grade, Food Grade, Technical Grade, and ACS Reagent Grade — packaged from single quarts to 55-gallon drums and 275- and 330-gallon IBC totes. A 55-gallon drum of 75% starts at $1,525, every order ships from our warehouse in Taylor, Texas with no hazmat fee and no minimum order, and most in-stock orders leave in 1–2 business days.

Choose a grade

The grade on each product page is the grade in the certificate, stated per SKU and never inferred. Concentration and grade are separate choices — most strengths from 5% to 85% are stocked in more than one grade, so pick the grade your specification requires first, then the strength your process wants.

Grade What picks it
USP Food Grade (75%, 85%) Meets the USP/FCC monograph — the specification beverage, food-processing, and dietary-supplement buyers require for acidulation and pH control
Food Grade (5%–50%) Pre-diluted working strengths of food-specification acid for process lines that dose below concentrate strength
Technical Grade (5%–85%) The industrial tier for metal prep and rust removal, water treatment, fertilizer chemistry, and general process work — including the 30% rust remover blended for direct use
ACS Reagent Grade (5%–85%) Certified to ACS specifications for procedures that name a reagent-grade acid

Why 75% exists — and when to buy it over 85%

85% phosphoric acid is the standard commercial concentrate, but it begins to crystallize around 70 °F — a drum stored in an unheated warehouse or shipped in winter can arrive partly solid. 75% stays liquid far below freezing, which is why cold-climate plants and winter buyers specify it — and it is cheaper per drum. If your process is water-sensitive and needs maximum P₂O₅ per gallon, take 85% and store it warm; if handling temperature is outside your control, 75% is the practical choice.

Drum and tote pricing

These are the live single-container prices as of 2026-08-17 — the same prices in the cart, with per-gallon economics at the volume breaks. A 55-gallon drum of 85% Technical Grade is $1,803 ($32.78/gal). The 5%–50% dilutions in every grade are priced on their product pages; standing-order volume is quoted at 512-365-6838.

Product 1 Gallon 5 Gallon 55-Gal Drum 275-Gal Tote
85% USP Food Grade $87 $303 $1,980 ($36.00/gal) — (—)
85% Technical Grade $83 $285 $1,803 ($32.78/gal) $8,910 ($32.40/gal)
85% ACS Reagent Grade $84 $294 $2,541 ($46.20/gal) $11,069 ($40.25/gal)
75% USP Food Grade $45 $166 $1,525 ($27.73/gal) $6,019 ($21.89/gal)
75% Technical Grade $45 $166 $1,525 ($27.73/gal) $6,019 ($21.89/gal)
30% Rust Remover — Technical Grade $49 $186 $1,628 ($29.60/gal) $6,764 ($24.60/gal)

How phosphoric acid ships

Phosphoric acid solution is a DOT-regulated corrosive: UN1805, Phosphoric acid solution, Hazard Class 8. Quarts and gallons ship by ground parcel; drums and totes move as LTL corrosive-class freight from Taylor, Texas on our regular carriers. Alliance Chemical does not add a hazmat fee at any package size — the price on the page is the price. Most in-stock orders ship within 1–2 business days.

COA and SDS

A lot-specific Certificate of Analysis — for the lot you receive, not a generic sample — is available for every product in this collection through the COA request page. Safety Data Sheets for every grade are in the SDS library; review the SDS before handling. Phosphoric acid is corrosive to skin and eyes and attacks ordinary steel — use compatible materials (316 stainless, HDPE, PVC) for storage and transfer.

Common applications

  • Rust removal and metal prep: phosphoric acid converts red iron oxide to a stable phosphate layer — the chemistry behind rust converters and pre-paint metal treatment.
  • Food and beverage acidulation: USP Food Grade acid provides tartness and pH control in beverages and processed foods, and cleans food-contact process equipment.
  • Water treatment: corrosion-control dosing and pH adjustment in municipal and industrial systems.
  • Fertilizer and chemical feedstock: the phosphorus source for phosphate salt production and agricultural formulation.

Why Buy From Alliance Chemical

Alliance Chemical is a wholesale phosphoric acid distributor shipping from Taylor, Texas. Single quarts and full tote quantities get the same treatment: lot-specific COA support, current SDS on every product, volume pricing printed on the page rather than hidden behind a quote form, and no hazmat fees.

Related: Sulfuric Acid, Hydrochloric Acid, Food-Grade Phosphoric Acid Guide.

Frequently Asked Questions

Where can I buy phosphoric acid?
Right here. Alliance stocks phosphoric acid from 5% to 85% in food/USP, technical and ACS reagent grades, in 1 quart, 1 gallon, 5, 15 and 55 gallon drums and 275 and 330 gallon totes. Ships from Texas in 1 to 2 business days with the SDS on every product page.
Which phosphoric acid grade should I buy?
85% technical for metal treatment and process work; 75% or 85% food grade when it touches food or beverage; 30% is the ready-to-use rust remover; 5% to 20% for labs and light cleaning; ACS reagent grade when an analytical method calls for it.
Is phosphoric acid for sale in bulk?
Yes. 55-gallon drums and 275-gallon and 330-gallon totes ship on a pallet by LTL freight. For multi-drum or recurring supply, use the quote form on any product page and we price it with freight.
Who can buy phosphoric acid?
Anyone. Alliance sells phosphoric acid online to businesses and individuals in food, USP, technical, and ACS grades, 5% to 85%, quart through tote. It is not a DEA listed chemical and no federal rule restricts who may buy it, so no license, permit, or purchase record is required. Follow the SDS.
How is phosphoric acid shipped?
Every strength, 5% to 85%, ships as hazmat: UN1805, Phosphoric acid solution, Class 8, Packing Group III, packed by staff trained to 49 CFR 172.704. Quarts and gallons ship UPS Ground as Limited Quantity, pails as regulated hazmat by UPS Ground, drums and totes by LTL freight.
What is phosphoric acid used for?
Phosphoric acid is used for rust conversion, metal treatment, food and beverage acidulation, pH adjustment, cleaning, descaling, and industrial process chemistry.
What is the difference between food grade and technical grade phosphoric acid?
Food or USP grades are selected when a regulated food, beverage, or formulation process requires that specification. Technical grade is used for industrial cleaning, pH control, and metal treatment where food-grade documentation is not required.
Can phosphoric acid remove rust?
Yes. Phosphoric acid can convert iron oxide and support rust-removal workflows on compatible metal surfaces when concentration, contact time, and rinsing are controlled.
Is phosphoric acid an oxidizing acid?
Phosphoric acid is generally considered a non-oxidizing mineral acid, unlike nitric acid. It is still corrosive and requires acid-rated handling controls.
Does phosphoric acid require hazmat shipping?
Shipping requirements depend on concentration, package size, destination, and transport mode. Review the product SDS and order details for the applicable classification.
Forklift moving pallets in a warehouse

Stock footage.

How it ships.

Regulated products are packed, marked, and labeled for hazmat transport, from one quart to a pallet of drums.

  • Most stocked orders ship in 1–2 business daysOrder cutoff: Mon-Thu 2 PM CT / Fri 12 PM CT
  • Hazmat packing, marking, and labelingPacked by staff trained under DOT rule 49 CFR 172.704
  • UPS Ground for bottles, jugs, and up to three pailsLTL freight for four or more pails, drums, and totes. Liftgate on request.
  • Ships with
  • UPS
  • FedEx Freight
  • ABF Freight
  • R+L Carriers
  • Saia
  • Southeastern Freight Lines
  • XPO

Buying for a company or agency?

Pay by card at the listed price, or order on Net 30 terms once your credit is approved. For NSN and contract requirements, send an RFQ.

CAGE code
1LT50
UEI
DCTCZDY3BLD3
Primary NAICS
424690
Ownership
Woman-Owned
Federal supply
DLA Supplier
Terms
Net 30 on approved credit, W-9 on request
Gloved hands strapping four blue chemical drums to a pallet at a warehouse loading dock
Illustration.

Safety data sheets and certificates.

Find an SDS or TDS by product name or CAS number. Certificates of analysis are free on request.

Find an SDS or COA

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