Sodium Hydroxide 50% Membrane Grade (Caustic Soda, Lye)

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$25.30

Sodium Hydroxide 50% Membrane Grade (Caustic Soda, Lye)

$25.30

Quick Answer

What is Sodium Hydroxide 50% Membrane Grade (Caustic Soda, Lye) used for, and what should buyers verify before ordering?

Sodium Hydroxide 50% Membrane Grade (Caustic Soda, Lye) is supplied at 49-51% in Technical Grade with UN 1824, DOT Class 8 . Buyers should confirm pack size, grade, SDS, COA needs, and freight requirements before purchase.

  • Assay: 49-51%
  • Grade: Technical Grade
  • UN number: UN 1824
  • DOT class: 8
  • Documents: SDS and lot-specific COA support
  • Shipping: UPS for small packs; LTL/FTL for pails, drums, totes, and bulk orders

Commercial Fulfillment Snapshot

Buy Sodium Hydroxide 50% Membrane Grade (Caustic Soda, Lye) with faster decisions and fewer back-and-forth emails.

Ships from Taylor, Texas. In-stock orders placed before 1:00 PM CT (Mon-Thu) and before 12:00 PM CT (Fri) typically ship within 1-2 business days. Order online 24/7.

Technical Documents

Lot-specific COA is issued per shipment batch.

Who Buys This
  • Water treatment facilities
  • Chemical manufacturers
  • Soap & cosmetic producers
  • Food processing plants
  • Textile manufacturing companies
Purity / Grade Guide
  • Membrane grade sodium hydroxide
  • 50% concentrated aqueous solution
  • Industrial & commercial applications
  • Verified purity, COA included
Pack Sizes
  • 1 Quart: lab & small jobs
  • 1 Gallon: shop & maintenance
  • 5 Gallon: production & regular use
  • 15 Gallon: mid-volume operations
  • 55 Gallon: bulk drum
  • 275 Gallon: high-volume tote
  • 330 Gallon: max-volume tote
SDS / COA / TDS
  • UN 1824 Class 8 packaging
  • Complete SDS included
  • Certificate of analysis provided
  • Corrosive material transport rating
Small Packs: UPS Ground nationwide for pints, quarts, and gallons.
LTL / FTL: ABF, SEFL, Saia, XPO, and partner carriers for pails, drums, totes, and full truckloads.
Support: Email or call for freight options, hazardous-material routing, and lead-time confirmation.

Product Overview

Sodium Hydroxide 50% Membrane Grade (Caustic Soda, Lye) is a highly concentrated, strongly alkaline liquid solution engineered for demanding industrial processes. This chemical intermediate, with molecular formula HNaO and molecular weight 39.997, plays an essential role in numerous chemical manufacturing, water treatment, and neutralization applications. As a premier industrial distributor, Alliance Chemical provides this high-purity solution to facilitate efficient processing across diverse sectors. Our 50% concentration provides a balance between high chemical activity and convenient liquid handling, eliminating the need to dissolve solid beads or flakes on-site.

Maintaining consistent concentration and purity is critical for industrial workflows. Our Sodium Hydroxide 50% solution is colorless and more dense than water, exhibiting strong alkalinity even in a 1% dilution. We ensure that every batch conforms strictly to chemical specifications to prevent unwanted process deviations. Safety Data Sheets (SDS) are provided with every order to ensure safe handling, and a Certificate of Analysis (COA) is always available upon request. Customers can easily find related alkaline compounds by visiting our Bases collection to source compatible raw materials for their operations.

Why This Grade

Membrane grade sodium hydroxide represents the highest standard for commercial liquid caustic soda, characterized by extremely low concentrations of salt (sodium chloride), chlorates, and carbonate impurities. This ultra-pure grade is produced using modern membrane cell electrolysis, which avoids the heavy metal contamination historically associated with mercury cells or the higher salt content typical of diaphragm cell processes. For industries like pulp and paper, textile manufacturing, and specialty chemical synthesis, utilizing membrane grade is necessary to protect sensitive catalytic systems and prevent unwanted secondary chemical reactions.

Choosing the incorrect grade or concentration of sodium hydroxide can lead to severe operational failures. Standard industrial-grade caustic soda often contains elevated levels of chloride and silica, which can cause rapid corrosion of stainless steel process piping and scale buildup in heat exchangers. Furthermore, using a lower concentration than 50% increases transportation costs per unit of active chemistry and alters the water balance in closed-loop chemical reactions. By selecting our Membrane Grade 50% solution, operators ensure maximum efficiency, minimize the risk of equipment fouling, and maintain precise control over their reaction stoichiometry.

Chemical Profile

CAS Number
1310-73-2
Chemical Formula
HNaO
Molecular Weight
39.997 g/mol
Boiling Point
greater than 266 °F at 760 mmHg (USCG, 1999)
Melting Point
604 °F (USCG, 1999)
Flash Point
N/A °C
Specific Gravity
1.5 at 68 °F (USCG, 1999) - Denser than water; will sink
Appearance
Sodium hydroxide solution appears as a colorless liquid. More dense than water. Contact may severely irritate skin, eyes, and mucous membranes. Toxic by ingestion. Corrosive to metals and tissue.
Solubility
111 % (NIOSH, 2024)
UN Number
UN1824
Hazard Class
Class 8
Packing Group
II
Proper Shipping Name
SODIUM HYDROXIDE SOLUTION
GHS Signal Word
Danger

Values sourced from Alliance Chemical's canonical chemistry registry. Certificate of Analysis (COA) per lot.

Industrial Applications

  • Chemical Synthesis: Serves as a primary alkaline reactant and pH regulator in the production of diverse organic and inorganic chemicals, including plastics, synthetic fibers, and sodium salts.
  • Pulp and Paper Processing: Utilized in the Kraft process for de-inking recycled fibers, bleaching wood pulp, and treating process water to maintain optimal digestion alkalinity.
  • Water and Wastewater Treatment: Employed to adjust pH levels, neutralize acidic effluent streams, and precipitate heavy metals from industrial wastewater discharges before environmental release.
  • Textile and Mercerizing: Applied in the mercerization process of cotton fibers to increase luster, improve tensile strength, and enhance dye affinity in industrial textile manufacturing.
  • Metal Cleaning and Etching: Used in metalworking to clean surface oils, degrease components, and perform controlled etching on aluminum surfaces during anodizing preparations.

Hazmat & Shipping

Sodium Hydroxide 50% Membrane Grade is classified as a regulated hazardous material due to its highly corrosive properties. For transport, it is designated as UN1824, Hazard Class 8, with a Packing Group of II, and the proper shipping name SODIUM HYDROXIDE SOLUTION. The signal word for this chemical is Danger. There are no GHS pictograms applicable in the authoritative record for this specific configuration. Compliance with Department of Transportation (DOT) regulations is strictly observed in every shipment we dispatch from our Texas facilities to guarantee secure delivery.

The hazard statements associated with this product are H290 (May be corrosive to metals) and H314 (Causes severe skin burns and eye damage). Proper safety measures are required under OSHA regulations. Personnel handling this substance must utilize appropriate Personal Protective Equipment (PPE) to mitigate risks. This includes chemical-resistant gloves, protective clothing, and a face shield. The primary precautionary statements to follow include P234 (Keep only in original packaging), P260 (Do not breathe mist or vapors), P280 (Wear protective gloves/clothing/eye protection), and P305+P351+P338 (In case of contact with eyes, rinse cautiously with water). For additional details on safe handling, explore our Sodium Hydroxide 50% product page to review material safety guidelines.

Handling & Storage

Proper storage is essential to prevent operational issues. Sodium hydroxide solutions of 50% concentration will begin to crystallize or freeze at approximately 54°F (12°C). Therefore, storage tanks and piping must be heat-traced or maintained in temperature-controlled environments to prevent freezing. Standard container materials should include high-density polyethylene (HDPE), polypropylene, or nickel alloys. Avoid any contact with aluminum, zinc, tin, or galvanized metals, as caustic soda reacts with these materials to generate flammable hydrogen gas. Keep containers tightly closed and isolated from strong acids and organic halogens.

Order & Documentation

Alliance Chemical ensures that every customer receives the documentation required for strict regulatory and quality compliance. We provide comprehensive logistic support for quantities ranging from quarts to bulk drums. A Safety Data Sheet (SDS) is provided with every order, and a Certificate of Analysis (COA) is always available upon request to verify physical and chemical properties. To proceed with your procurement, please use our online tools to Request a Quote or Download the SDS.

Why Buy from Alliance Chemical

Since 1997, Alliance Chemical has supplied premium industrial chemicals from Taylor, Texas under CAGE Code 1LT50, with a COA and SDS included on every order. For industrial use only.

Related reading

Car Dipping: The 3-Tank Process That Strips Paint and Kills Rust on a Whole Car Body — restoration shops use NaOH 50% Membrane Grade diluted to 25–30% as the hot Tank 1 caustic bath in the 3-tank car dipping process.

Co-Dose Application

Using this product with alum for industrial wastewater pH control

Caustic soda is the standard co-dose partner for Aluminum Sulfate 50% in industrial wastewater treatment — the alkaline neutralizer that holds pH in the 5.5–7.5 coagulation sweet spot as the acidic alum drives pH downward. Read our complete technical guide on the chemistry, jar-testing protocol, and EPA 40 CFR 433 compliance framework.

Read the technical guide →
Property Value
Molecular Weight 40.00
Formula NaOH
Assay 49-51%
Grade Technical Grade
Form Liquid solution
Solubility Soluble in water
Appearance Clear, colorless liquid
Melting Point 323
Boiling Point 100
Specific Gravity 1.20
Industry Water Treatment, Chemical Manufacturing, Personal Care, Food Industry, Textile Industry

Frequently Asked Questions About Sodium Hydroxide 50% Membrane Grade (Caustic Soda, Lye)

What is Sodium Hydroxide 50% Membrane Grade (Caustic Soda, Lye) and what is its chemical formula?
Sodium Hydroxide 50% Membrane Grade (Caustic Soda, Lye) is a chemical compound with the molecular formula HNaO, registered under CAS Number 1310-73-2 by the Chemical Abstracts Service (PubChem), with a molecular weight of 39.997 g/mol. Alliance Chemical supplies Sodium Hydroxide 50% Membrane Grade (Caustic Soda, Lye) in Membrane grade for laboratory, industrial, and commercial applications.
What are the physical properties of Sodium Hydroxide 50% Membrane Grade (Caustic Soda, Lye)?
According to the NIOSH Pocket Guide to Chemical Hazards, Sodium Hydroxide 50% Membrane Grade (Caustic Soda, Lye) has a clear, caustic liquid appearance. It has a melting point of 323°C°C, a boiling point of 1388°C°C, a flash point of N/A. Solubility: Complete water solubility, moderate organic solvent.
What grade and purity of Sodium Hydroxide 50% Membrane Grade (Caustic Soda, Lye) does Alliance Chemical offer?
Alliance Chemical offers Sodium Hydroxide 50% Membrane Grade (Caustic Soda, Lye) in Membrane grade with a purity assay of 50%. Every lot ships with a Certificate of Analysis (COA) and Safety Data Sheet (SDS) prepared in accordance with OSHA Hazard Communication Standard 29 CFR 1910.1200 and GHS Revision 7. Download SDS.
What are common industrial applications of Sodium Hydroxide 50% Membrane Grade (Caustic Soda, Lye)?
Sodium Hydroxide 50% Membrane Grade (Caustic Soda, Lye) has applications in laboratory research, manufacturing, and industrial processing.Alliance Chemical provides the documentation and quality certifications required for use in regulated environments.
What PPE is required when handling Sodium Hydroxide 50% Membrane Grade (Caustic Soda, Lye)?
OSHA-mandated PPE per 29 CFR 1910.132-138:Chemical-resistant gloves (20+ mil neoprene or PVC), full face shield over safety goggles (ANSI Z87.1), acid-resistant apron or chemical suit, closed-toe chemical-resistant footwear. Respiratory protection (organic vapor cartridge) required in areas exceeding PEL/TLV per 29 CFR 1910.134. Emergency eyewash station and safety shower must be accessible within 10 seconds per ANSI Z358.1. Consult the SDS available from Alliance Chemical for complete PPE requirements.
What are the storage requirements for Sodium Hydroxide 50% Membrane Grade (Caustic Soda, Lye)?
Store perOSHA 29 CFR 1910.106: Approved flammable storage cabinet, maximum 60 gallons per cabinet, grounding/bonding required. Temperature range:15-25°C. Segregate from:acids, aluminum, zinc. Maximum storage:2-3 years unopened.
What is the emergency spill procedure for Sodium Hydroxide 50% Membrane Grade (Caustic Soda, Lye)?
Emergency response per EPA SPCC (40 CFR 112) and OSHA 29 CFR 1910.120: (1) Alert personnel, evacuate area to 100 feet. (2) Eliminate ignition sources if flammable. (3) Don PPE per SDS Section 8. (4) Stop leak if safe; use emergency shutoffs. (5) Contain with non-combustible absorbent materials, dike with sand/earth. (6)Neutralize with citric acid or acetic acid (5% solution). (7) Collect in DOT-approved containers, label as hazardous waste. Check 40 CFR 302.4 for Reportable Quantity. Emergency: Chemtel 1-800-255-3924 (24/7). Non-emergency: Alliance Chemical 512-365-6838.
What is the DOT shipping classification for Sodium Hydroxide 50% Membrane Grade (Caustic Soda, Lye)?
DOT Classification per 49 CFR 172.101:UN1824, Hazard Class8, Packing GroupII. Requires: Hazmat shipping papers (49 CFR 172.200), UN specification packaging (49 CFR 173), hazmat labels (172.400). Alliance Chemical ships all orders in DOT-compliant packaging with proper documentation.
How must Sodium Hydroxide 50% Membrane Grade (Caustic Soda, Lye) waste be disposed?
Disposal per RCRA (40 CFR 261-265):Characteristic waste D002 (Corrosive, pH ≤2 or ≥12.5). Generator requirements: EPA ID number required if >100 kg/month (40 CFR 262.12). Use EPA-permitted Treatment, Storage, Disposal Facility (TSDF). Never discharge to sewer without POTW written approval (40 CFR 403). Container disposal: Triple rinse (40 CFR 261.7), offer for reconditioning/recycling. State regulations may be more stringent — check with your local environmental agency. Consult the Alliance Chemical SDS for product-specific disposal guidance.
Does Alliance Chemical provide an SDS and COA for Sodium Hydroxide 50% Membrane Grade (Caustic Soda, Lye)?
Yes. Alliance Chemical provides a Safety Data Sheet (SDS) and Certificate of Analysis (COA) for every lot of Sodium Hydroxide 50% Membrane Grade (Caustic Soda, Lye). The SDS is prepared in accordance with OSHA Hazard Communication Standard 29 CFR 1910.1200 and the Globally Harmonized System (GHS) Revision 7, covering all 16 required sections including hazard identification, first aid measures, firefighting measures, handling and storage, exposure controls, and regulatory information. The SDS is available for download directly from this product page. COAs are available upon request by contacting Alliance Chemical at 512-365-6838.