Sodium Hydroxide 50% Solution ACS Grade

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$22.09

Sodium Hydroxide 50% Solution ACS Grade

$22.09

Quick Answer

What is Sodium Hydroxide 50% Solution ACS Grade used for, and what should buyers verify before ordering?

Sodium Hydroxide 50% Solution ACS Grade is supplied at 49-51% in ACS Grade with UN 1824, DOT Class 8 . Buyers should confirm pack size, grade, SDS, COA needs, and freight requirements before purchase.

  • Assay: 49-51%
  • Grade: ACS Grade
  • UN number: UN 1824
  • DOT class: 8
  • Documents: SDS and lot-specific COA support
  • Shipping: UPS for small packs; LTL/FTL for pails, drums, totes, and bulk orders

Commercial Fulfillment Snapshot

Buy Sodium Hydroxide 50% Solution ACS Grade with faster decisions and fewer back-and-forth emails.

Ships from Taylor, Texas. In-stock orders placed before 1:00 PM CT (Mon-Thu) and before 12:00 PM CT (Fri) typically ship within 1-2 business days. Order online 24/7.

Technical Documents

Lot-specific COA is issued per shipment batch.

Who Buys This
  • Analytical testing laboratories
  • Pharmaceutical QC departments
  • Research institutions
  • Chemical manufacturing facilities
  • University chemistry programs
Purity / Grade Guide
  • ACS Grade meets reagent standards
  • High purity for lab applications
  • Precise assay 50% concentration verified by COA
  • Suitable for analytical procedures
Pack Sizes
  • 1 Quart: lab & small jobs
  • 1 Gallon: shop & maintenance
  • 5 Gallon: production & regular use
  • 15 Gallon: mid-volume operations
  • 55 Gallon: bulk drum
  • 275 Gallon: high-volume tote
  • 330 Gallon: max-volume tote
SDS / COA / TDS
  • SDS included
  • COA provided
  • UN 1824 Class 8 PG II
  • ACS reagent grade certification
Small Packs: UPS Ground nationwide for pints, quarts, and gallons.
LTL / FTL: ABF, SEFL, Saia, XPO, and partner carriers for pails, drums, totes, and full truckloads.
Support: Email or call for freight options, hazardous-material routing, and lead-time confirmation.

Product Overview

Sodium Hydroxide 50% Solution ACS Grade is a highly concentrated, aqueous alkaline solution designed for demanding laboratory and industrial processes where purity is paramount. This inorganic compound — represented by the chemical formula HNaO and possessing a molecular weight of 39.997 — is a fundamental reagent utilized across multiple technical sectors. Known commonly as caustic soda solution, it is formulated to deliver precise molarity and reliable alkalinity. At this 50% concentration, the solution provides an efficient balance of high chemical activity and ease of liquid handling, bypassing the dissolution steps required for solid beads or flakes.

We supply this high-purity solution to facilitate seamless integration into automated dosing systems, titration setups, and chemical synthesis pathways. It appears as a colorless, odorless liquid that is denser than water, which requires specific handling procedures to ensure safety and process consistency. Alliance Chemical distributes this product under our bases collection to support rigorous testing protocols, pH control, and raw material synthesis. Whether you are managing municipal processing facilities, industrial manufacturing plants, or analytical testing environments, our sodium hydroxide solution offers the stable concentration needed for exact, repeatable chemical reactions.

Why This Grade

The ACS Grade designation indicates that this product meets the strict purity specifications established by the American Chemical Society. For chemical processes requiring a 50% concentration, electing to use a lower technical grade can introduce unwanted heavy metals, carbonates, or halides. These impurities act as catalyst poisons or interfere with delicate analytical instruments, leading to skewed titration results or failed synthesis runs. Using the exact 50% concentration ensures consistent viscosity and reaction rates, preventing unexpected exothermic spikes that can occur when manually diluting solid sodium hydroxide.

In industrial workflows, choosing an incorrect grade can lead to severe system failure modes, such as the precipitation of insoluble salts that clog precise dosing pumps and analytical columns. This ACS Grade solution features strictly controlled trace element levels, protecting your equipment from premature scaling and contamination. Furthermore, a 50% concentration is critical for processes that require a high concentration of hydroxide ions without introducing excessive water, which would otherwise dilute the reaction medium. Maintaining this strict balance prevents analytical drift and preserves the integrity of your technical operations.

Chemical Profile

CAS Number
1310-73-2
Chemical Formula
HNaO
Molecular Weight
39.997 g/mol
Boiling Point
greater than 266 °F at 760 mmHg (USCG, 1999)
Melting Point
604 °F (USCG, 1999)
Specific Gravity
1.5 at 68 °F (USCG, 1999) - Denser than water; will sink
Appearance
Sodium hydroxide solution appears as a colorless liquid. More dense than water. Contact may severely irritate skin, eyes, and mucous membranes. Toxic by ingestion. Corrosive to metals and tissue.
Solubility
111 % (NIOSH, 2024)
UN Number
UN1824
Hazard Class
Class 8
Packing Group
II
Proper Shipping Name
SODIUM HYDROXIDE SOLUTION
GHS Signal Word
Danger

Values sourced from Alliance Chemical's canonical chemistry registry. Certificate of Analysis (COA) per lot.

Industrial Applications

  • Chemical Synthesis: Serving as a primary reagent in the synthesis of organic compounds, sodium salts, and specialized surfactants where raw material purity directly influences end-product quality.
  • pH Adjustment and Neutralization: Neutralizing acidic waste streams in chemical processing facilities, industrial manufacturing plants, and high-purity wastewater treatment systems to maintain strict discharge compliance.
  • Cellulose and Paper Processing: Facilitating the digestion of wood pulp and the extraction of lignin in specialty paper manufacturing processes that require precise alkaline conditions.
  • Metal Finishing and Etching: Acting as a strong alkaline bath for de-greasing, cleaning, and chemical etching of aluminum and other metal surfaces prior to anodizing or coating.
  • Saponification in Soap Manufacture: Promoting the controlled hydrolysis of fats and oils in the precision manufacturing of specialized soaps, detergents, and industrial cleaning agents.

Hazmat & Shipping

Sodium Hydroxide 50% Solution ACS Grade is classified as a hazardous material for transport. It is regulated under DOT guidelines as UN1824, Hazard Class 8 (Corrosive), Packing Group II. The proper shipping name is SODIUM HYDROXIDE SOLUTION. The designated GHS Signal Word for this chemical is Danger. Because of its high alkalinity and corrosive nature, it poses significant safety risks if not handled with absolute care. Our logistics team ensures that all shipments comply strictly with federal hazmat regulations, utilizing certified packaging designed to withstand corrosive liquids. We manage every step of the transport process to ensure safe, compliant delivery to your facility.

This chemical carries hazard statements H290 (May be corrosive to metals) and H314 (Causes severe skin burns and eye damage). Consequently, operators must wear comprehensive personal protective equipment (PPE). Appropriate PPE includes chemical-resistant gloves, protective clothing, and a full face shield or safety goggles to prevent any skin or eye contact. In compliance with safety regulations, a Safety Data Sheet (SDS) is provided with every order to detail these hazards and emergency response protocols. Ensure your facility is equipped with functioning eye wash stations and safety showers in all areas where this strong alkaline solution is stored or handled.

Handling & Storage

Store Sodium Hydroxide 50% Solution ACS Grade in a cool, dry, well-ventilated area, ideally keeping the storage temperature above 60 °F (16 °C) to prevent the solution from freezing or crystallizing, as 50% caustic soda has a relatively high freezing point. Use only compatible containers, such as high-density polyethylene (HDPE), polypropylene, or nickel alloys. Avoid contact with incompatible materials, including strong acids, organic halogen compounds, nitro compounds, and reactive metals like aluminum, zinc, and tin, as these reactions can generate dangerous amounts of flammable hydrogen gas.

Order & Documentation

We provide the high-quality chemical reagents required to keep your laboratory and industrial operations running smoothly. A Certificate of Analysis (COA) is available upon request for every batch to verify product purity, and a Safety Data Sheet (SDS) is provided with every order. To secure your supply of Sodium Hydroxide 50% Solution ACS Grade, you can Request a Quote for bulk volumes or Download the SDS for your safety records.

Why Buy from Alliance Chemical

Since 1997, Alliance Chemical has supplied premium industrial chemicals from Taylor, Texas under CAGE Code 1LT50, with a COA and SDS included on every order. For industrial use only.

Co-Dose Application

Sodium hydroxide as the pH-control partner to alum

In industrial wastewater treatment, Sodium Hydroxide 50% co-doses with Aluminum Sulfate 50% to hold pH in the 5.5–7.5 coagulation sweet spot as the acidic alum drives pH downward. For the complete chemistry, jar-testing protocol, and three real-world cost-transformation case studies, read our technical guide on alum in metal fabrication wastewater.

Read the technical guide →
Property Value
Molecular Weight 40.00
Formula NaOH
Assay 49-51%
Grade ACS Grade
Form Liquid
Solubility Soluble in water
Appearance Clear, colorless to slightly yellow liquid
Melting Point 318
Boiling Point 1390
Specific Gravity 1.52
Industry Water Treatment, Industrial, Cosmetics, Analytical Chemistry, Industrial Cleaning

Frequently Asked Questions About Sodium Hydroxide 50% Solution ACS Grade

What is Sodium Hydroxide 50% Solution ACS Grade and what is its chemical formula?
Sodium Hydroxide 50% Solution ACS Grade is a chemical compound with the molecular formula HNaO, registered under CAS Number 1310-73-2 by the Chemical Abstracts Service (PubChem), with a molecular weight of 39.997 g/mol. Alliance Chemical supplies Sodium Hydroxide 50% Solution ACS Grade in ACS Reagent grade for laboratory, industrial, and commercial applications.
What are the physical properties of Sodium Hydroxide 50% Solution ACS Grade?
According to the NIOSH Pocket Guide to Chemical Hazards, Sodium Hydroxide 50% Solution ACS Grade is supplied as a clear, colorless liquid. It has a melting point of 318°C (604.4°F)°C, a boiling point of 1390°C (2534°F)°C. The specific gravity is 1.53 relative to water. Solubility: Highly soluble in water and alcohol.
What grade and purity of Sodium Hydroxide 50% Solution ACS Grade does Alliance Chemical offer?
Alliance Chemical offers Sodium Hydroxide 50% Solution ACS Grade in ACS Reagent grade with a purity assay of 50%. Every lot ships with a Certificate of Analysis (COA) and Safety Data Sheet (SDS) prepared in accordance with OSHA Hazard Communication Standard 29 CFR 1910.1200 and GHS Revision 7. Download SDS.
What are common industrial applications of Sodium Hydroxide 50% Solution ACS Grade?
Sodium Hydroxide 50% Solution ACS Grade serves a wide range of sectors, including Industrial & Manufacturing, and Water & Environmental.Alliance Chemical provides the documentation and quality certifications required for use in regulated environments.
What PPE is required when handling Sodium Hydroxide 50% Solution ACS Grade?
OSHA-mandated PPE per 29 CFR 1910.132-138:Chemical-resistant gloves (20+ mil neoprene or PVC), full face shield over safety goggles (ANSI Z87.1), acid-resistant apron or chemical suit, closed-toe chemical-resistant footwear. Emergency eyewash station and safety shower must be accessible within 10 seconds per ANSI Z358.1. Consult the SDS available from Alliance Chemical for complete PPE requirements.
What are the storage requirements for Sodium Hydroxide 50% Solution ACS Grade?
Store perOSHA 29 CFR 1910.1450: Dedicated corrosives cabinet with secondary containment (110% volume per EPA 40 CFR 264.175). Temperature range:15-25°C. Segregate from:acids, aluminum, zinc. Maximum storage:2-3 years unopened.
What is the emergency spill procedure for Sodium Hydroxide 50% Solution ACS Grade?
Emergency response per EPA SPCC (40 CFR 112) and OSHA 29 CFR 1910.120: (1) Alert personnel, evacuate area to 50 feet. (2) Eliminate ignition sources if flammable. (3) Don PPE per SDS Section 8. (4) Stop leak if safe; use emergency shutoffs. (5) Contain with non-combustible absorbent materials, dike with sand/earth. (6)Neutralize with citric acid or acetic acid (5% solution). (7) Collect in DOT-approved containers, label as hazardous waste. Check 40 CFR 302.4 for Reportable Quantity. Emergency: Chemtel 1-800-255-3924 (24/7). Non-emergency: Alliance Chemical 512-365-6838.
What is the DOT shipping classification for Sodium Hydroxide 50% Solution ACS Grade?
DOT Classification per 49 CFR 172.101:UN1824, Hazard Class8, Packing GroupII. Requires: Hazmat shipping papers (49 CFR 172.200), UN specification packaging (49 CFR 173), hazmat labels (172.400). Alliance Chemical ships all orders in DOT-compliant packaging with proper documentation.
How must Sodium Hydroxide 50% Solution ACS Grade waste be disposed?
Disposal per RCRA (40 CFR 261-265):Characteristic waste D002 (Corrosive, pH ≤2 or ≥12.5). Generator requirements: EPA ID number required if >100 kg/month (40 CFR 262.12). Use EPA-permitted Treatment, Storage, Disposal Facility (TSDF). Never discharge to sewer without POTW written approval (40 CFR 403). Container disposal: Triple rinse (40 CFR 261.7), offer for reconditioning/recycling. State regulations may be more stringent — check with your local environmental agency. Consult the Alliance Chemical SDS for product-specific disposal guidance.
Does Alliance Chemical provide an SDS and COA for Sodium Hydroxide 50% Solution ACS Grade?
Yes. Alliance Chemical provides a Safety Data Sheet (SDS) and Certificate of Analysis (COA) for every lot of Sodium Hydroxide 50% Solution ACS Grade. The SDS is prepared in accordance with OSHA Hazard Communication Standard 29 CFR 1910.1200 and the Globally Harmonized System (GHS) Revision 7, covering all 16 required sections including hazard identification, first aid measures, firefighting measures, handling and storage, exposure controls, and regulatory information. The SDS is available for download directly from this product page. COAs are available upon request by contacting Alliance Chemical at 512-365-6838.