Hydrochloric Acid 37% ACS Reagent Grade

Category : Acids

$32.45
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Hydrochloric Acid 37% ACS Reagent Grade

$32.45

Quick Answer

What is Hydrochloric Acid 37% ACS Reagent Grade used for, and what should buyers verify before ordering?

Hydrochloric Acid 37% ACS Reagent Grade is supplied at 36.5-37.5% in ACS Grade with UN 1789, DOT Class 8 . Buyers should confirm pack size, grade, SDS, COA needs, and freight requirements before purchase.

  • Assay: 36.5-37.5%
  • Grade: ACS Grade
  • UN number: UN 1789
  • DOT class: 8
  • Documents: SDS and lot-specific COA support
  • Shipping: UPS for small packs; LTL/FTL for pails, drums, totes, and bulk orders

Commercial Fulfillment Snapshot

Buy Hydrochloric Acid 37% ACS Reagent Grade with faster decisions and fewer back-and-forth emails.

Ships from Taylor, Texas. In-stock orders placed before 1:00 PM CT (Mon-Thu) and before 12:00 PM CT (Fri) typically ship within 1-2 business days. Order online 24/7.

Technical Documents

Live, always-current docs · lot-specific COA issued per shipment batch.

Who Buys This
  • Analytical chemistry laboratories
  • Pharmaceutical manufacturers
  • Quality control departments
  • Research institutions
  • University chemistry programs
Purity / Grade Guide
  • ACS Reagent Grade purity
  • 37% concentration verified by COA guarantee
  • Laboratory analytical applications
  • Meets ACS specifications
Pack Sizes
  • 1 Quart: lab & small jobs
  • 1 Gallon: shop & maintenance
  • 5 Gallon: production & regular use
  • 15 Gallon: mid-volume operations
  • 55 Gallon: bulk drum
  • 275 Gallon: high-volume tote
  • 330 Gallon: max-volume tote
SDS / COA / TDS
  • UN 1789 Class 8 shipping
  • Safety Data Sheet included
  • Certificate of Analysis provided
  • ACS compliance documentation
Small Packs: UPS Ground nationwide for pints, quarts, and gallons.
LTL / FTL: ABF, SEFL, Saia, XPO, and partner carriers for pails, drums, totes, and full truckloads.
Support: Email or call for freight options, hazardous-material routing, and lead-time confirmation.

Product Overview

Hydrochloric Acid 37% ACS Reagent Grade is a highly corrosive, strong mineral acid with diverse applications across industrial, laboratory, and manufacturing sectors. Chemically represented as ClH with a molecular weight of 36.46, this aqueous solution consists of hydrogen chloride gas dissolved in water. As a fundamental chemical reagent, it plays a critical role in pH adjustment, chemical synthesis, and metal processing. Industrial users rely on the precise 37% concentration to achieve predictable reaction stoichiometry and consistent manufacturing outcomes. Our acids collection includes various grades to meet specific operational demands, and this high-purity product is manufactured to meet rigorous quality standards, ensuring minimal impurities and reliable performance in demanding chemical environments.

The physical properties of this solution are highly characteristic, appearing as a colorless, watery liquid with a sharp, irritating odor that requires strict containment and ventilation controls. Since it is denser than water, it sinks and mixes completely, presenting unique handling challenges compared to weaker acids. The product's volatility and the generation of irritating hydrogen chloride vapors necessitate specialized storage and transfer equipment to protect personnel and infrastructure. Alliance Chemical provides this high-purity acid in multiple packaging configurations, ranging from convenient quarts to industrial-scale quantities, catering to both research facilities and bulk manufacturing plants nationwide.

Why This Grade

Selecting the ACS Reagent grade of hydrochloric acid at a 37% concentration is essential for applications where trace chemical impurities could compromise analytical results or foul sensitive catalysts. ACS Reagent grade specifications mandate strict limits on heavy metals, free chlorine, sulfate, sulfite, and ammonium, which ensures that the chemical composition remains highly consistent from lot to lot. Using a lower-grade acid, such as technical or muriatic grade, introduces uncontrolled variables like iron or organic residues. These contaminants can poison catalysts in organic synthesis, interfere with spectrophotometric analyses, or cause unwanted side reactions in high-precision manufacturing.

Furthermore, the 37% concentration represents the practical limit of hydrogen chloride gas solubility in water at ambient temperatures. This concentration is the industry standard for concentrated hydrochloric acid, offering the maximum chemical activity per unit volume. Utilizing an incorrect concentration, or a grade with wider tolerances, often leads to process failures. For instance, in laboratory titrations or standard solution preparation, slight variations in acid concentration can result in significant calculation errors, ruined batches, and lost operating time. By standardizing on our ACS Reagent grade 37% solution, facility operators and laboratory technicians can eliminate these failure modes and ensure absolute process control.

Chemical Profile

CAS Number
7647-01-0
Chemical Formula
ClH
Molecular Weight
36.46 g/mol
Boiling Point
123 °F at 760 mmHg (USCG, 1999)
Melting Point
-174.6 °F (Melting point is -13.7 °F for a 39.17% weight/weight solution.) (EPA, 1998)
Flash Point
Does not apply °C
Specific Gravity
1.05 at 59 °F for 10.17% weight/weight solution (EPA, 1998) - Denser than water; will sink
Appearance
Hydrochloric acid, solution is a colorless watery liquid with a sharp, irritating odor. Consists of hydrogen chloride, a gas, dissolved in water. Sinks and mixes with water. Produces irritating vapor. (USCG, 1999)
Solubility
82.3 g/100 g at 32 °F (NTP, 1992)
UN Number
UN1789
Hazard Class
Class 8
Packing Group
II
Proper Shipping Name
Hydrochloric acid
GHS Signal Word
Danger

Values sourced from Alliance Chemical's canonical chemistry registry. Certificate of Analysis (COA) per lot.

Industrial Applications

  • Chemical Synthesis: Serves as a fundamental reactant in the production of organic compounds like vinyl chloride and various inorganic chlorides. When you purchase Hydrochloric Acid 37% ACS Reagent Grade, you are guaranteed high-purity inputs for chemical synthesis.
  • Catalyst Regeneration: Used extensively to regenerate ion-exchange resins in water treatment systems and catalytic systems within the petrochemical sector.
  • Metal Pickling: Effective for removing rust, scale, and iron oxide impurities from steel surfaces prior to galvanizing or electroplating.
  • Analytical Chemistry: Employed in laboratory testing, wet chemical analysis, and pH adjustment during sensitive titration procedures across research facilities.
  • Ore Processing: Applied in metallurgical processes for the extraction and refining of rare metals and precious ores from raw materials. We support diverse sectors through our dedicated industrial manufacturing solutions.

Hazmat & Shipping

Hydrochloric Acid 37% ACS Reagent Grade is highly regulated due to its corrosive and toxic nature. For transport, it is classified under DOT regulations as UN1789, Hazard Class 8, Packing Group II. The proper shipping name is Hydrochloric acid. The associated GHS signal word is Danger. Because this material is classified as regulated, it requires specialized transport protocols, certified packaging, and compliant labeling to ensure safe transit from our facilities to your delivery site. Standard ground shipments must adhere strictly to 49 CFR regulations, which govern the volume limits and containment specifications for corrosive liquids.

Safety is paramount when handling this substance. Due to the GHS hazard statement H314, which indicates that this material causes severe skin burns and eye damage, personnel must wear comprehensive personal protective equipment (PPE). This includes a chemical-resistant apron, heavy-duty neoprene or nitrile gloves, and a full-face shield. Furthermore, because of hazard statement H331, which warns that the chemical is toxic if inhaled, all operations must be conducted in a well-ventilated area or inside a certified fume hood. A respiratory protection program must be implemented if airborne exposure limits are exceeded. We recommend consulting the comprehensive safety documentation before handling this highly reactive acid.

Handling & Storage

Store Hydrochloric Acid 37% ACS Reagent Grade in a cool, dry, and well-ventilated area, preferably at temperatures between 59°F and 77°F to minimize the release of irritating fumes. Keep containers tightly closed and store them in secondary containment systems constructed of acid-resistant materials. This acid is highly incompatible with strong oxidizing agents, strong bases, metals, amines, and cyanides. Contact with metals can generate highly flammable hydrogen gas, creating an explosion hazard. Ensure all transfer equipment, piping, and valves are composed of compatible materials such as fluoropolymers, PVC, or glass-lined steel, as standard metals will suffer rapid degradation and corrosion.

Order & Documentation

Alliance Chemical ensures that all documentation is fully transparent and easily accessible for our commercial clients. We maintain rigorous quality control standards, and a Certificate of Analysis (COA) is available upon request for every batch we ship. Additionally, a comprehensive Safety Data Sheet (SDS) is provided with every order to support your facility's safety and compliance protocols. To proceed with your procurement, please use our online portal. You can Request a Quote for bulk volumes or Download the SDS to review compliance requirements.

Why Buy from Alliance Chemical

Since 1997, Alliance Chemical has supplied premium industrial chemicals from Taylor, Texas under CAGE Code 1LT50, with a COA and SDS included on every order. For industrial use only.

Learn more about Hydrochloric Acid 37% ACS Reagent Grade

Related Reading

Not sure whether you need ACS Reagent or Technical Grade? Our guide breaks down the purity specs, the cost-per-grade math, and which jobs actually require reagent purity: Hydrochloric Acid 37%: ACS Reagent vs Technical Grade.

Property Value
Molecular Weight 36.46
Formula HCl
Assay 36.5-37.5%
Grade ACS Grade
Flash Point Does not apply
Form Liquid
Solubility Completely soluble in water
Appearance Colorless to pale yellow liquid
Melting Point -114
Boiling Point 110
Specific Gravity 1.19
Industry Water Treatment, Pharmaceutical, Industrial, Research Laboratory, Chemical Manufacturing

Frequently Asked Questions About Hydrochloric Acid 37% ACS Reagent Grade

What is Hydrochloric Acid 37% ACS Reagent Grade and what is its chemical formula?
Hydrochloric Acid 37% ACS Reagent Grade is a chemical compound with the molecular formula ClH, registered under CAS Number 7647-01-0 by the Chemical Abstracts Service (PubChem), with a molecular weight of 36.46 g/mol. Alliance Chemical supplies Hydrochloric Acid 37% ACS Reagent Grade in ACS Reagent grade for laboratory, industrial, and commercial applications.
What are the physical properties of Hydrochloric Acid 37% ACS Reagent Grade?
According to the NIOSH Pocket Guide to Chemical Hazards, Hydrochloric Acid 37% ACS Reagent Grade is supplied as a clear, colorless corrosive liquid. It has a melting point of -114°C (-173.2°F)°C, a boiling point of 108°C (226.4°F)°C, a flash point of Does not apply. Solubility: Fully miscible with water, most organic solvents.
What grade and purity of Hydrochloric Acid 37% ACS Reagent Grade does Alliance Chemical offer?
Alliance Chemical offers Hydrochloric Acid 37% ACS Reagent Grade in ACS Reagent grade with a purity assay of 37%. Every lot ships with a Certificate of Analysis (COA) and Safety Data Sheet (SDS) prepared in accordance with OSHA Hazard Communication Standard 29 CFR 1910.1200 and GHS Revision 7. Download SDS.
What are common industrial applications of Hydrochloric Acid 37% ACS Reagent Grade?
Hydrochloric Acid 37% ACS Reagent Grade serves a wide range of sectors, including Chemical Processing, Industrial & Manufacturing, and Lab & Research.Alliance Chemical provides the documentation and quality certifications required for use in regulated environments.
What PPE is required when handling Hydrochloric Acid 37% ACS Reagent Grade?
OSHA-mandated PPE per 29 CFR 1910.132-138:Chemical-resistant gloves (20+ mil neoprene or PVC), full face shield over safety goggles (ANSI Z87.1), acid-resistant apron or chemical suit, closed-toe chemical-resistant footwear. Respiratory protection (organic vapor cartridge) required in areas exceeding PEL/TLV per 29 CFR 1910.134. Emergency eyewash station and safety shower must be accessible within 10 seconds per ANSI Z358.1. Consult the SDS available from Alliance Chemical for complete PPE requirements.
What are the storage requirements for Hydrochloric Acid 37% ACS Reagent Grade?
Store perOSHA 29 CFR 1910.106: Approved flammable storage cabinet, maximum 60 gallons per cabinet, grounding/bonding required. Temperature range:15-25°C. Segregate from:bases, reactive metals, organic materials. Maximum storage:2-3 years unopened.
What is the emergency spill procedure for Hydrochloric Acid 37% ACS Reagent Grade?
Emergency response per EPA SPCC (40 CFR 112) and OSHA 29 CFR 1910.120: (1) Alert personnel, evacuate area to 100 feet. (2) Eliminate ignition sources if flammable. (3) Don PPE per SDS Section 8. (4) Stop leak if safe; use emergency shutoffs. (5) Contain with non-combustible absorbent materials, dike with sand/earth. (6)Carefully neutralize with sodium bicarbonate (5-10% solution), monitor exothermic reaction. (7) Collect in DOT-approved containers, label as hazardous waste. Reportable Quantity: 5000 lbs. Emergency: Chemtel 1-800-255-3924 (24/7). Non-emergency: Alliance Chemical 512-365-6838.
What is the DOT shipping classification for Hydrochloric Acid 37% ACS Reagent Grade?
DOT Classification per 49 CFR 172.101:UNUN1789, Hazard Class8, Packing GroupII. Requires: Hazmat shipping papers (49 CFR 172.200), UN specification packaging (49 CFR 173), hazmat labels (172.400). Alliance Chemical ships all orders in DOT-compliant packaging with proper documentation.
How must Hydrochloric Acid 37% ACS Reagent Grade waste be disposed?
Disposal per RCRA (40 CFR 261-265):Characteristic waste D002 (Corrosive, pH ≤2 or ≥12.5). Generator requirements: EPA ID number required if >100 kg/month (40 CFR 262.12). Use EPA-permitted Treatment, Storage, Disposal Facility (TSDF). Never discharge to sewer without POTW written approval (40 CFR 403). Container disposal: Triple rinse (40 CFR 261.7), offer for reconditioning/recycling. State regulations may be more stringent — check with your local environmental agency. Consult the Alliance Chemical SDS for product-specific disposal guidance.
Does Alliance Chemical provide an SDS and COA for Hydrochloric Acid 37% ACS Reagent Grade?
Yes. Alliance Chemical provides a Safety Data Sheet (SDS) and Certificate of Analysis (COA) for every lot of Hydrochloric Acid 37% ACS Reagent Grade. The SDS is prepared in accordance with OSHA Hazard Communication Standard 29 CFR 1910.1200 and the Globally Harmonized System (GHS) Revision 7, covering all 16 required sections including hazard identification, first aid measures, firefighting measures, handling and storage, exposure controls, and regulatory information. The SDS is available for download directly from this product page. COAs are available upon request by contacting Alliance Chemical at 512-365-6838.