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Chemical Comparison

Nitric Acid vs Phosphoric Acid

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Comprehensive comparison of Nitric Acid and Phosphoric Acid including physical properties, applications, safety considerations, and pricing. Alliance Chemical supplies both chemicals in various grades and concentrations.

Quick Comparison Summary

Nitric Acid

CAS:
7697-37-2
Formula:
HNO₃
Available:
65%, 40%, 25%, 20%, 5%
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VS

Phosphoric Acid

CAS:
7664-38-2
Formula:
H₃PO₄
Available:
85%
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Physical Properties

Physical & Chemical Properties Comparison

Property Nitric Acid Phosphoric Acid Key Difference
Boiling Point 83°C 158 °C Phosphoric Acid boils 75°C higher
Flash Point ⚠️ N/A N/A Data not available for direct comparison
Density 1.5129 g/cm³ 1.834 g/cm³ Phosphoric Acid is denser
Water Solubility Miscible with water Miscible with water Both fully water soluble
pH < 1 (concentrated) < 1 (concentrated) Nitric Acid is more acidic
Molecular Weight 63.01 g/mol 98.00 g/mol Phosphoric Acid is heavier molecule
Melting Point -42°C (86% solution) 42.35°C Phosphoric Acid melts 84.35°C higher
Vapor Pressure 48 mmHg at 20°C (86% solution) N/A Data not available for direct comparison
Auto-ignition Temp ⚠️ N/A N/A Data not available for direct comparison
Vapor Density 2.2 (air = 1) 3.4 (air = 1) Phosphoric Acid vapors sink more
Appearance Clear, colorless to slightly yellow liquid Clear, colorless, viscous liquid
Odor Pungent, suffocating Odorless

Data sourced from PubChem (NIH), OSHA Technical Guidelines, and Alliance Chemical laboratory analysis. Last verified April 2026.

Applications

Applications & Use Cases

Nitric Acid Best For:

  • Production of fertilizers
  • Nitration reactions
  • Metal etching
  • Laboratory reagent
  • Production of explosives

Phosphoric Acid Best For:

  • Fertilizer production
  • Metal surface treatment
  • Rust removal
  • pH adjustment
  • Food additive

Choosing Between Them

The right choice depends on your specific application, required purity, and handling capabilities. Contact our team for guidance on which chemical best fits your needs.

Safety

Safety & Handling Comparison

Storage Requirements

Always store in original containers in a cool, well-ventilated area per NFPA 30 guidelines. Refer to each product's SDS for specific storage temperature ranges and incompatible materials.

PPE Requirements

At minimum: chemical-resistant gloves, safety goggles, and adequate ventilation per OSHA 29 CFR 1910.132-138. Check each SDS below for chemical-specific PPE requirements.

Fire Hazard

Consult SDS for specific fire hazard information.

Recommendation

Which Chemical Should You Choose?

Decision Snapshot

Decision Factor Better Fit Why
Evaporation Profile Nitric Acid Lower boiling point supports faster flash-off.
Fire Safety Margin Check SDS Flash-point data is incomplete for one or both products.
Application Breadth Tie Compares distinct listed use cases to avoid generic recommendations.
Purity Flexibility Standard grades Based on availability of 99%+ concentration options in current product metadata.

Choose Nitric Acid if:

  • You specifically need support for production of fertilizers applications.
  • You specifically need support for nitration reactions applications.
  • You want a faster-evaporating solvent for quick-dry production steps.

Choose Phosphoric Acid if:

  • You specifically need support for fertilizer production applications.
  • You specifically need support for metal surface treatment applications.
  • You need a higher-boiling solvent that stays in-process longer.

Commercial & Fulfillment Snapshot

Built for purchasing teams that need predictable dispatch, compliant documentation, and freight flexibility from parcel to full truckload.

Procurement Advantage Nitric Acid Phosphoric Acid
Grade & Concentration Coverage 65% to 5% with industrial/lab procurement support. 85% with industrial/lab procurement support.
Packaging Depth small packs through bulk freight quantities for parcel, pallet, and truckload planning. small packs through bulk freight quantities for parcel, pallet, and truckload planning.
Dispatch SLA Order by 1 PM CT (Mon-Thu) or noon CT Friday for same-business-day outbound from Taylor, TX. Order by 1 PM CT (Mon-Thu) or noon CT Friday for same-business-day outbound from Taylor, TX.
Freight Optionality UPS Ground for small packs plus LTL/FTL lanes through ABF, SEFL, Saia, XPO, and partner carriers. UPS Ground for small packs plus LTL/FTL lanes through ABF, SEFL, Saia, XPO, and partner carriers.
Compliance Readiness SDS ready now; COA/TDS support available pre-PO and post-order. SDS ready now; COA/TDS support available pre-PO and post-order.
Bulk Procurement CTA Request bulk quote or call (512) 365-6838. Request bulk quote or call (512) 365-6838.

Need Help Deciding? Our technical team can help you choose the right chemical for your specific application. Email sales@alliancechemical.com for expert guidance.

Andre Taki, Lead Product Specialist at Alliance Chemical

Andre Taki

Lead Product Specialist, Alliance Chemical

Practice Leader, Cooling Chemistry

Andre Taki is Lead Product Specialist at Alliance Chemical, a DoD Bronze Medal DLA supplier. He holds DOT Hazardous Materials certification (49 CFR 172.704) and brings 20+ years of chemical industry experience across industrial manufacturing, laboratory and research, data center thermal management, and government / DoD procurement. He specializes in chemical dilution, heat-transfer fluid selection, hazmat logistics, and grade specification (ACS, USP, food, technical).

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Alliance Chemical supplies both Nitric Acid and Phosphoric Acid in various grades and package sizes.

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