n-Heptane 99% ACS

Category : Hydrocarbons

$26.40
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Hexane ACS Reagent Grade
From $30.42
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n-Heptane 99% ACS

$26.40

Quick Answer

What is n-Heptane 99% ACS used for, and what should buyers verify before ordering?

n-Heptane 99% ACS is supplied at 99-100.5% in ACS Grade with UN 1206, DOT Class 3 . Buyers should confirm pack size, grade, SDS, COA needs, and freight requirements before purchase.

  • Assay: 99-100.5%
  • Grade: ACS Grade
  • UN number: UN 1206
  • DOT class: 3
  • Documents: SDS and lot-specific COA support
  • Shipping: UPS for small packs; LTL/FTL for pails, drums, totes, and bulk orders

Commercial Fulfillment Snapshot

Buy n-Heptane 99% ACS with faster decisions and fewer back-and-forth emails.

Ships from Taylor, Texas. In-stock orders placed before 1:00 PM CT (Mon-Thu) and before 12:00 PM CT (Fri) typically ship within 1-2 business days. Order online 24/7.

Technical Documents

Lot-specific COA is issued per shipment batch.

Who Buys This
  • Analytical chemistry labs
  • Pharmaceutical manufacturers
  • Food & flavor extractors
  • Research laboratories
  • Industrial cleaning operations
Purity / Grade Guide
  • ACS Grade meets reagent standards
  • 99% concentration verified by COA assured
  • HPLC & analytical applications
  • Pharmaceutical synthesis compatible
Pack Sizes
  • 1 Pint: sample & testing
  • 1 Liter: lab & bench scale
  • 5 Gallon: production & regular use
  • 55 Gallon: bulk drum
SDS / COA / TDS
  • UN 1206 Class 3 packaging
  • SDS safety data included
  • COA
  • ACS specification compliance
Small Packs: UPS Ground nationwide for pints, quarts, and gallons.
LTL / FTL: ABF, SEFL, Saia, XPO, and partner carriers for pails, drums, totes, and full truckloads.
Support: Email or call for freight options, hazardous-material routing, and lead-time confirmation.

Product Overview

n-Heptane 99% ACS is a high-purity, straight-chain alkane hydrocarbon that serves as an essential solvent and reagent in both industrial processes and laboratory environments. Characterized by its clear, colorless appearance and its distinct petroleum-like odor, this solvent exhibits highly predictable physical behaviors due to its 99% minimum assay. As a non-polar solvent, it is completely insoluble in water but highly miscible with most organic solvents, making it a critical choice for extraction procedures, chemical synthesis, and precision cleaning applications where moisture must be strictly avoided.

Alliance Chemical distributes this premium chemical within our hydrocarbons collection to meet the demands of facilities requiring consistent solvent performance. This specific grade of n-heptane is critical for applications that cannot tolerate the trace impurities found in lower-grade technical solvents, which can compromise reactions or leave residues on sensitive components. Whether used as a mobile phase in chromatography, an extraction solvent for natural products, or a baseline standard for octane rating determinations, our n-heptane delivers the reliability and chemical consistency demanded by modern industrial operations across North America.

Why This Grade

The ACS (American Chemical Society) grade designation guarantees that this n-heptane meets or exceeds the strict purity specifications established by the ACS Committee on Analytical Reagents. For processes that require a 99% concentration, utilizing a lower-purity technical or industrial grade introduces volatile organic compounds, branched isomers, and trace metals that can interfere with analytical results or poison catalytic systems. High-precision extraction and laboratory analysis demand this exact level of purity to ensure baseline stability and eliminate the risk of unwanted chemical side reactions that alter final product yields.

Selecting an incorrect grade of heptane can lead to catastrophic process failure modes, such as the deposition of non-volatile residues on precision mechanical parts, or cross-contamination in pharmaceutical solvent recrystallization. Lower-grade solvents often contain higher fractions of isomers or aromatics that alter the boiling point and evaporation rate, leading to incomplete solvent recovery and inconsistent extraction profiles. By standardizing on our 99% ACS grade, operators prevent these costly quality deviations, ensure compliance with standard operating procedures, and guarantee that the chemical's physical properties align precisely with expected technical parameters.

Chemical Profile

CAS Number
142-82-5
Chemical Formula
C7H16
Molecular Weight
100.20 g/mol
Boiling Point
209.1 °F at 760 mmHg (USCG, 1999)
Melting Point
-131 °F (USCG, 1999)
Flash Point
25 °F (USCG, 1999)
Specific Gravity
0.6838 at 68 °F (USCG, 1999) - Less dense than water; will float
Appearance
N-heptane is a clear colorless liquids with a petroleum-like odor. Flash point 25 °F. Less dense than water and insoluble in water. Vapors heavier than air.
Solubility
0.0003 % (NIOSH, 2024)
UN Number
UN1206
Hazard Class
Class 3
Packing Group
II
Proper Shipping Name
Heptanes
GHS Signal Word
Danger

Values sourced from Alliance Chemical's canonical chemistry registry. Certificate of Analysis (COA) per lot.

Industrial Applications

  • Laboratory Chromatography: Utilized as a mobile phase solvent in liquid chromatography and gas chromatography to separate non-polar compounds with high resolution.
  • Precision Extraction: Serving as an efficient extraction solvent for botanical oils, fats, and natural products without leaving harmful chemical residues behind.
  • Adhesives and Sealants: Employed as a carrier solvent in the formulation of high-performance industrial adhesives, rubber cements, and specialized coatings.
  • Metal Cleaning and Degreasing: Used in precision manufacturing to clean and degrease electronic components and mechanical parts without causing oxidation or corrosion.
  • Chemical Synthesis: Acting as an inert reaction medium or solvent for organic synthesis, polymerizations, and organometallic reactions requiring non-polar environments.

Hazmat & Shipping

n-Heptane 99% ACS is a highly flammable liquid regulated for transport as UN1206, Hazard Class 3, Packing Group II, with the proper shipping name Heptanes. The signal word for this material is Danger. Standard safety protocols mandate that personnel handling this solvent wear appropriate personal protective equipment (PPE) to mitigate risks associated with its hazard statements. This includes chemical splash goggles, nitrile or Viton gloves to protect against skin irritation (H315), and flame-resistant clothing to safeguard against the severe fire hazard (H225). Due to the risk of aspiration (H304) and drowsiness or dizziness (H336) from vapor inhalation, operations must occur under a certified fume hood or in areas equipped with robust mechanical ventilation systems.

Because n-Heptane is highly toxic to aquatic life with long-lasting effects (H410), containment measures must be strictly enforced during transport and transfer. Our shipping procedures fully comply with DOT regulations, ensuring that all containers meet rigorous pressure and material compatibility standards. A Safety Data Sheet (SDS) is provided with every order to ensure that your safety officer and material handling team have direct access to comprehensive hazard and handling guidelines. All shipments are dispatched via certified hazmat carriers to guarantee safe, legal, and compliant transit to your facility.

Handling & Storage

Storage of n-heptane must occur in a cool, dry, well-ventilated area away from direct sunlight, open flames, and incompatible substances such as strong oxidizing agents, halogens, and strong acids. Ideal storage temperatures should be maintained within a controlled range, typically between 50°F and 85°F, to minimize vapor pressure buildup and prevent thermal expansion. Standard container compatibility requires the use of steel, stainless steel, or approved high-density polyethylene (HDPE) containers, while avoiding materials like natural rubber, neoprene, and low-density plastics that degrade upon contact. Grounding and bonding of all transfer equipment are strictly required to prevent electrostatic discharge, a critical risk given the product's low flash point of 25 °F.

Order & Documentation

Alliance Chemical provides comprehensive support for industrial sourcing, offering flexible packaging configurations from pints to larger bulk quantities to match your specific operational scale. We offer a Certificate of Analysis (COA) available upon request for every batch to confirm purity specs and ensure compliance with your internal quality control protocols. To secure your supply or review critical safety guidelines, you can Request a Quote directly or Download the SDS. Our technical customer service team is ready to assist with bulk pricing and custom shipping arrangements.

Why Buy from Alliance Chemical

Since 1997, Alliance Chemical has supplied premium industrial chemicals from Taylor, Texas under CAGE Code 1LT50, with a COA and SDS included on every order. For industrial use only.

Property Value
Molecular Weight 100.20
Formula C7H16
Assay 99-100.5%
Grade ACS Grade
Flash Point 4°C
Form Liquid
Solubility Insoluble in water, soluble in organic solvents
Appearance Clear, colorless liquid
Melting Point -90.6
Boiling Point 98.0
Specific Gravity 0.684
Industry Analytical Chemistry, Pharmaceutical, Food Industry, Research Laboratory, Industrial

Frequently Asked Questions About n-Heptane 99% ACS

What is n-Heptane 99% ACS and what is its chemical formula?
n-Heptane 99% ACS is a chemical compound with the molecular formula C7H16, registered under CAS Number 142-82-5 by the Chemical Abstracts Service (PubChem), with a molecular weight of 100.20 g/mol. Alliance Chemical supplies n-Heptane 99% ACS in ACS Reagent grade for laboratory, industrial, and commercial applications.
What are the physical properties of n-Heptane 99% ACS?
According to the NIOSH Pocket Guide to Chemical Hazards, n-Heptane 99% ACS is supplied as a clear, colorless liquid. It has a melting point of '-91°C°C, a boiling point of 98°C°C, a flash point of 4°C. The specific gravity is 0.684 relative to water. Solubility: Insoluble in water, soluble in organic solvents.
What grade and purity of n-Heptane 99% ACS does Alliance Chemical offer?
Alliance Chemical offers n-Heptane 99% ACS in ACS Reagent grade with a purity assay of 99%. Every lot ships with a Certificate of Analysis (COA) and Safety Data Sheet (SDS) prepared in accordance with OSHA Hazard Communication Standard 29 CFR 1910.1200 and GHS Revision 7. Download SDS.
What are common industrial applications of n-Heptane 99% ACS?
n-Heptane 99% ACS serves a wide range of sectors, including Energy & Petroleum, and Industrial & Manufacturing.Alliance Chemical provides the documentation and quality certifications required for use in regulated environments.
What PPE is required when handling n-Heptane 99% ACS?
OSHA-mandated PPE per 29 CFR 1910.132-138:Nitrile gloves (8+ mil), safety goggles, flame-resistant clothing, grounded footwear, closed-toe chemical-resistant footwear. Respiratory protection (organic vapor cartridge) required in areas exceeding PEL/TLV per 29 CFR 1910.134. Emergency eyewash station and safety shower must be accessible within 10 seconds per ANSI Z358.1. Consult the SDS available from Alliance Chemical for complete PPE requirements.
What are the storage requirements for n-Heptane 99% ACS?
Store perOSHA 29 CFR 1910.106: Approved flammable storage cabinet, maximum 60 gallons per cabinet, grounding/bonding required. Temperature range:15-25°C. Segregate from:oxidizers, ignition sources. Maximum storage:2-3 years unopened.
What is the emergency spill procedure for n-Heptane 99% ACS?
Emergency response per EPA SPCC (40 CFR 112) and OSHA 29 CFR 1910.120: (1) Alert personnel, evacuate area to 100 feet. (2) Eliminate ignition sources if flammable. (3) Don PPE per SDS Section 8. (4) Stop leak if safe; use emergency shutoffs. (5) Contain with non-combustible absorbent materials, dike with sand/earth. (6)Absorb with vermiculite or commercial spill kits. (7) Collect in DOT-approved containers, label as hazardous waste. Check 40 CFR 302.4 for Reportable Quantity. Emergency: Chemtel 1-800-255-3924 (24/7). Non-emergency: Alliance Chemical 512-365-6838.
What is the DOT shipping classification for n-Heptane 99% ACS?
DOT Classification per 49 CFR 172.101:UNUN1206, Hazard Class3, Packing GroupII. Requires: Hazmat shipping papers (49 CFR 172.200), UN specification packaging (49 CFR 173), hazmat labels (172.400). Alliance Chemical ships all orders in DOT-compliant packaging with proper documentation.
How must n-Heptane 99% ACS waste be disposed?
Disposal per RCRA (40 CFR 261-265):Characteristic waste D001 (Ignitable, flash point <60°C). Generator requirements: EPA ID number required if >100 kg/month (40 CFR 262.12). Use EPA-permitted Treatment, Storage, Disposal Facility (TSDF). Never discharge to sewer without POTW written approval (40 CFR 403). Container disposal: Triple rinse (40 CFR 261.7), offer for reconditioning/recycling. State regulations may be more stringent — check with your local environmental agency. Consult the Alliance Chemical SDS for product-specific disposal guidance.
Does Alliance Chemical provide an SDS and COA for n-Heptane 99% ACS?
Yes. Alliance Chemical provides a Safety Data Sheet (SDS) and Certificate of Analysis (COA) for every lot of n-Heptane 99% ACS. The SDS is prepared in accordance with OSHA Hazard Communication Standard 29 CFR 1910.1200 and the Globally Harmonized System (GHS) Revision 7, covering all 16 required sections including hazard identification, first aid measures, firefighting measures, handling and storage, exposure controls, and regulatory information. The SDS is available for download directly from this product page. COAs are available upon request by contacting Alliance Chemical at 512-365-6838.