Hydrofluorosilicic Acid 23% (HFS)

Category : Acids

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Hydrofluorosilicic Acid 23% (HFS)

$17.02

Quick Answer

What is Hydrofluorosilicic Acid 23% (HFS) used for, and what should buyers verify before ordering?

Hydrofluorosilicic Acid 23% (HFS) is supplied at 22.5-23.5% in Technical grade with UN 1760, DOT Class 8 . Buyers should confirm pack size, grade, SDS, COA needs, and freight requirements before purchase.

  • Assay: 22.5-23.5%
  • Grade: Technical
  • UN number: UN 1760
  • DOT class: 8
  • Documents: SDS and lot-specific COA support
  • Shipping: UPS for small packs; LTL/FTL for pails, drums, totes, and bulk orders

Commercial Fulfillment Snapshot

Buy Hydrofluorosilicic Acid 23% (HFS) with faster decisions and fewer back-and-forth emails.

Ships from Taylor, Texas. In-stock orders placed before 1:00 PM CT (Mon-Thu) and before 12:00 PM CT (Fri) typically ship within 1-2 business days. Order online 24/7.

Technical Documents

Lot-specific COA is issued per shipment batch.

Who Buys This
  • Municipal water treatment facilities
  • Industrial chemical manufacturers
  • Metal finishing & electroplating shops
  • Environmental remediation companies
  • Laboratory testing facilities
Purity / Grade Guide
  • Industrial & lab applications
  • Verified purity, COA included
  • Suitable for commercial processes
  • 23% concentration for balanced handling
Pack Sizes
  • 1 Quart: lab & small jobs
  • 1 Gallon: shop & maintenance
  • 5 Gallon: production & regular use
  • 15 Gallon: mid-volume operations
  • 55 Gallon: bulk drum
  • 275 Gallon: high-volume tote
  • 330 Gallon: max-volume tote
SDS / COA / TDS
  • UN 1778 Class 8 packaging
  • Complete SDS with every order
  • Certificate of Analysis included
  • Corrosive liquid transport requirements
Small Packs: UPS Ground nationwide for pints, quarts, and gallons.
LTL / FTL: ABF, SEFL, Saia, XPO, and partner carriers for pails, drums, totes, and full truckloads.
Support: Email or call for freight options, hazardous-material routing, and lead-time confirmation.

Product Overview

Hydrofluorosilicic Acid 23% (HFS) is a highly corrosive, aqueous solution of fluorosilicic acid, widely utilized across various industrial and municipal sectors. As a primary agent for industrial fluoridation, this inorganic compound requires precise handling and deep technical understanding due to its strong acidic profile and fuming nature. Alliance Chemical supplies high-quality HFS to meet the rigorous demands of industrial processing, surface preparation, and pH adjustment within our catalog of industrial acids.

Characterized as a colorless, fuming liquid with a penetrating, pungent odor, this chemical is highly reactive and requires robust materials of construction for storage and transport. Alliance Chemical coordinates safe and efficient distribution of this asset across our network, ensuring that your chemical supply chain remains uninterrupted. We provide access to comprehensive documentation, helping industrial operations maintain regulatory compliance while managing hazardous materials. Whether utilized in glass etching, metal cleaning, or municipal water fluoridation, this compound delivers consistent, high-strength performance across diverse manufacturing landscapes.

Why This Grade

The 23% concentration of Hydrofluorosilicic Acid is the standard industrial dilution optimized for stability, handling convenience, and material compatibility. Lower concentrations introduce excess water into industrial processes, which can dilute active baths and compromise the efficiency of surface treatments or chemical synthesis. Conversely, higher concentrations of fluorosilicic acid exhibit significantly higher vapor pressures, making them highly volatile, prone to excessive outgassing, and extremely dangerous to store and handle without highly specialized pressurized equipment. Purchasing the pre-formulated 23% concentration provides the optimal balance between chemical activity and operational safety.

Using an incorrect or unverified concentration can lead to severe operational failure modes, including the rapid degradation of process piping, under-fluoridation in municipal applications, or incomplete descaling in metal finishing operations. Standardizing on Alliance Chemical's Hydrofluorosilicic Acid 23% (HFS) ensures predictable dosing metrics, allowing automated monitoring systems to maintain exact chemical limits. Unrefined or off-spec grades can introduce heavy metal contaminants, leading to catalyst poisoning or unwanted secondary precipitates in your chemical reactions. By choosing this carefully controlled 23% dilution, facilities minimize deposit risks in dosing pumps and protect downstream mechanical infrastructure from premature corrosive failure.

Chemical Profile

CAS Number
16961-83-4
Chemical Formula
F6H2Si
Molecular Weight
144.091 g/mol
Boiling Point
212 °F at 760 mmHg (water) approx. (USCG, 1999)
Melting Point
-4 °F (USCG, 1999)
Specific Gravity
1.3 at 77 °F (approx.) (USCG, 1999) - Denser than water; will sink
Appearance
Fluorosilicic acid appears as a colorless fuming liquid with a penetrating pungent odor. Corrosive to metals and tissue. Both the fumes and very short contact with the liquid can cause severe and painful burns. Used in water fluoridation, in hardening cement and ceramics, as a wood preservative.
Solubility
DECOMP AT MP; DELIQUESCENT; WHITE CRYSTALS; SOL IN ALKALI; SOL IN COLD AND HOT WATER /DIHYDRATE/
UN Number
UN1778
Hazard Class
Class 8
Packing Group
II
Proper Shipping Name
Fluorosilicic acid
GHS Signal Word
DANGER

Values sourced from Alliance Chemical's canonical chemistry registry. Certificate of Analysis (COA) per lot.

Industrial Applications

  • Municipal Water Fluoridation: Employed by municipal water systems to adjust fluoride levels to standard target concentrations for municipal water treatment programs, read more about our industrial water treatment products.
  • Metal Cleaning and Etching: Utilized in the metal finishing industry for oxide removal, surface preparation, and etching of silicon wafers in electronics.
  • Ceramics and Cement Hardening: Formulated into industrial concrete treatments to accelerate curing times, harden surfaces, and improve overall structural density.
  • Wood Preservation: Used as an active ingredient in wood preservation formulations to protect structural timbers from wood-boring insects and rot.
  • Chemical Intermediate Synthesis: Serving as a critical precursor for manufacturing aluminum fluoride, synthetic cryolite, and other specialized fluorinated compounds.

Hazmat & Shipping

Hydrofluorosilicic Acid 23% is highly regulated for transport due to its aggressive corrosive properties toward metals and biological tissue. It is officially classified under United States Department of Transportation (DOT) and international regulations as UN1778, Hazard Class 8, Packing Group II, with the proper shipping name Fluorosilicic acid. The mandatory signal word is DANGER. Alliance Chemical coordinates all logistics in strict compliance with hazmat shipping mandates, utilizing dedicated carriers and DOT-approved containers to ensure safe transit from our facilities to your receiving dock.

Because this substance carries the hazard statement H314 (Causes severe skin burns and eye damage), personnel must utilize rigorous personal protective equipment (PPE) during any transfer or handling operations. Mandated safety gear includes chemical-resistant splash goggles, full-face shields, heavy-duty neoprene or nitrile gloves, and acid-resistant aprons or full protective suits. Standard operating procedures must dictate that a safety shower and eye wash station be immediately accessible in the handling area. Proper respiratory protection, such as a self-contained breathing apparatus or an acid-gas respirator, must be worn if fumes or vapors exceed permissible exposure limits.

Handling & Storage

Storage of Hydrofluorosilicic Acid 23% must occur within a controlled temperature range, ideally between 40°F and 90°F, to prevent crystallization and minimize fuming. Compatible container materials include high-density polyethylene (HDPE), polypropylene, or rubber-lined steel; glass, stoneware, and most common metals are highly incompatible and will suffer rapid corrosive attack. Keep containers tightly closed in a dry, cool, and well-ventilated area, away from strong bases, strong oxidizing agents, and reactive metals. Secondary containment is highly recommended to mitigate spill risks.

Order & Documentation

At Alliance Chemical, we prioritize regulatory transparency and operational safety for all clients. A detailed Certificate of Analysis (COA) is available upon request to verify physical and chemical specifications for your specific lot, and a safety data sheet (SDS) is provided with every order we ship. To proceed with your procurement needs, you can Request a Quote or Download the SDS to review safe handling guidelines.

Why Buy from Alliance Chemical

Since 1997, Alliance Chemical has supplied premium industrial chemicals from Taylor, Texas under CAGE Code 1LT50, with a COA and SDS included on every order. For industrial use only.

Property Value
Molecular Weight 144.28
Formula H2SiF6
Assay 22.5-23.5%
Grade Technical
Form Liquid
Solubility Soluble in water
Appearance Colorless liquid
Melting Point -20
Boiling Point 100
Specific Gravity 1.15
Industry Water Treatment, Industrial Chemistry, Manufacturing, Environmental Management, Metal Finishing

Frequently Asked Questions About Hydrofluorosilicic Acid 23% (HFS)

What is Hydrofluorosilicic Acid 23% (HFS) and what is its chemical formula?
Hydrofluorosilicic Acid 23% (HFS) is a chemical compound with the molecular formula F6H2Si, registered under CAS Number 16961-83-4 by the Chemical Abstracts Service (PubChem), with a molecular weight of 144.091 g/mol. Alliance Chemical supplies Hydrofluorosilicic Acid 23% (HFS) in Technical grade for laboratory, industrial, and commercial applications.
What are the physical properties of Hydrofluorosilicic Acid 23% (HFS)?
According to the NIOSH Pocket Guide to Chemical Hazards, Hydrofluorosilicic Acid 23% (HFS) is supplied as a colorless, fuming liquid. It has a melting point of -20°C (-4°F)°C, a boiling point of 108°C (226.4°F)°C. The specific gravity is 1.12 relative to water. Solubility: Soluble in water and alcohol.
What grade and purity of Hydrofluorosilicic Acid 23% (HFS) does Alliance Chemical offer?
Alliance Chemical offers Hydrofluorosilicic Acid 23% (HFS) in Technical grade with a purity assay of 23%. Every lot ships with a Certificate of Analysis (COA) and Safety Data Sheet (SDS) prepared in accordance with OSHA Hazard Communication Standard 29 CFR 1910.1200 and GHS Revision 7. Download SDS.
What are common industrial applications of Hydrofluorosilicic Acid 23% (HFS)?
Hydrofluorosilicic Acid 23% (HFS) serves a wide range of sectors, including Industrial & Manufacturing, and Water & Environmental.Alliance Chemical provides the documentation and quality certifications required for use in regulated environments.
What PPE is required when handling Hydrofluorosilicic Acid 23% (HFS)?
OSHA-mandated PPE per 29 CFR 1910.132-138:Chemical-resistant gloves (20+ mil neoprene or PVC), full face shield over safety goggles (ANSI Z87.1), acid-resistant apron or chemical suit, closed-toe chemical-resistant footwear. Emergency eyewash station and safety shower must be accessible within 10 seconds per ANSI Z358.1. Consult the SDS available from Alliance Chemical for complete PPE requirements.
What are the storage requirements for Hydrofluorosilicic Acid 23% (HFS)?
Store perOSHA 29 CFR 1910.1450: Dedicated corrosives cabinet with secondary containment (110% volume per EPA 40 CFR 264.175). Temperature range:15-25°C. Segregate from:bases, reactive metals, organic materials. Maximum storage:2-3 years unopened.
What is the emergency spill procedure for Hydrofluorosilicic Acid 23% (HFS)?
Emergency response per EPA SPCC (40 CFR 112) and OSHA 29 CFR 1910.120: (1) Alert personnel, evacuate area to 50 feet. (2) Eliminate ignition sources if flammable. (3) Don PPE per SDS Section 8. (4) Stop leak if safe; use emergency shutoffs. (5) Contain with non-combustible absorbent materials, dike with sand/earth. (6)Carefully neutralize with sodium bicarbonate (5-10% solution), monitor exothermic reaction. (7) Collect in DOT-approved containers, label as hazardous waste. Check 40 CFR 302.4 for Reportable Quantity. Emergency: Chemtel 1-800-255-3924 (24/7). Non-emergency: Alliance Chemical 512-365-6838.
What is the DOT shipping classification for Hydrofluorosilicic Acid 23% (HFS)?
DOT Classification per 49 CFR 172.101:UNUN1778, Hazard Class8, Packing GroupII. Requires: Hazmat shipping papers (49 CFR 172.200), UN specification packaging (49 CFR 173), hazmat labels (172.400). Alliance Chemical ships all orders in DOT-compliant packaging with proper documentation.
How must Hydrofluorosilicic Acid 23% (HFS) waste be disposed?
Disposal per RCRA (40 CFR 261-265):Characteristic waste D002 (Corrosive, pH ≤2 or ≥12.5). Generator requirements: EPA ID number required if >100 kg/month (40 CFR 262.12). Use EPA-permitted Treatment, Storage, Disposal Facility (TSDF). Never discharge to sewer without POTW written approval (40 CFR 403). Container disposal: Triple rinse (40 CFR 261.7), offer for reconditioning/recycling. State regulations may be more stringent — check with your local environmental agency. Consult the Alliance Chemical SDS for product-specific disposal guidance.
Does Alliance Chemical provide an SDS and COA for Hydrofluorosilicic Acid 23% (HFS)?
Yes. Alliance Chemical provides a Safety Data Sheet (SDS) and Certificate of Analysis (COA) for every lot of Hydrofluorosilicic Acid 23% (HFS). The SDS is prepared in accordance with OSHA Hazard Communication Standard 29 CFR 1910.1200 and the Globally Harmonized System (GHS) Revision 7, covering all 16 required sections including hazard identification, first aid measures, firefighting measures, handling and storage, exposure controls, and regulatory information. The SDS is available for download directly from this product page. COAs are available upon request by contacting Alliance Chemical at 512-365-6838.