Citric Acid 50% Solution

Category : Acids

$140.00
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Citric Acid 50% Solution

$140.00

Quick Answer

What is Citric Acid 50% Solution used for, and what should buyers verify before ordering?

Citric Acid 50% Solution is supplied at 49-51% in Reagent grade with UN 1760, DOT Class 8 . Buyers should confirm pack size, grade, SDS, COA needs, and freight requirements before purchase.

  • Assay: 49-51%
  • Grade: Reagent
  • UN number: UN 1760
  • DOT class: 8
  • Documents: SDS and lot-specific COA support
  • Shipping: UPS for small packs; LTL/FTL for pails, drums, totes, and bulk orders

Commercial Fulfillment Snapshot

Buy Citric Acid 50% Solution with faster decisions and fewer back-and-forth emails.

Ships from Taylor, Texas. In-stock orders placed before 1:00 PM CT (Mon-Thu) and before 12:00 PM CT (Fri) typically ship within 1-2 business days. Order online 24/7.

Technical Documents

Live, always-current docs · lot-specific COA issued per shipment batch.

Who Buys This
  • Food & beverage manufacturers
  • Industrial cleaning companies
  • Pharmaceutical formulators
  • Cosmetic & personal care makers
  • Laboratory & research facilities
Purity / Grade Guide
  • Industrial & lab applications
  • Verified purity, COA included
  • Suitable for commercial processes
  • 50% concentration verified by COA
Pack Sizes
  • 1 Quart: lab & small jobs
  • 1 Gallon: shop & maintenance
  • 5 Gallon: production & regular use
  • 15 Gallon: mid-volume operations
  • 55 Gallon: bulk drum
  • 275 Gallon: high-volume tote
  • 330 Gallon: max-volume tote
SDS / COA / TDS
  • Safety Data Sheet included
  • Certificate of Analysis provided
  • Non-regulated ground shipment
  • GHS hazard classification data
Small Packs: UPS Ground nationwide for pints, quarts, and gallons.
LTL / FTL: ABF, SEFL, Saia, XPO, and partner carriers for pails, drums, totes, and full truckloads.
Support: Email or call for freight options, hazardous-material routing, and lead-time confirmation.

Product Overview

Citric Acid 50% Solution is a concentrated liquid formulation of 2-hydroxypropane-1,2,3-tricarboxylic acid. This solution provides an efficient, ready-to-use liquid source of citric acid, eliminating the operational challenges associated with dissolving dry crystalline powder in industrial workflows. Formulated with high-purity raw materials, this 50% concentration is designed for precise pH control, metal surface treatments, and scale removal across diverse commercial sectors. By procuring pre-diluted solutions, operators reduce manual handling, dust inhalation risks, and batch-to-batch variation, ensuring consistent industrial chemical processing.

As a primary organic acid, this solution performs key roles in metal cleaning, agricultural formulations, and industrial water treatment. It acts as an effective chelating agent, binding multi-valent metal ions to prevent precipitation and scaling in piping systems. The liquid format allows for automated dosing and metered integration directly into existing process lines. Alliance Chemical supplies this chemical in various packaging volumes—from 1-quart containers to multiple 1-gallon cases—to accommodate specific operation scales of Citric Acid 50% Solution. We maintain rigorous quality control standards in our acids collection to deliver dependable chemistry for all technical, manufacturing, and industrial applications.

Why This Grade

Selecting a 50% concentration liquid format over dry crystalline forms is critical for maintaining process efficiency and dosing accuracy. At 50% concentration, the solution remains stable under standard operating temperatures without premature crystallization or precipitation out of the liquid phase. Using a pre-formulated liquid minimizes preparation errors that occur during manual dry dissolution, such as local concentration spikes or incomplete dissolving of granules. This concentration offers the optimal balance between high active acid content and manageable viscosity, making it highly compatible with standard industrial metering pumps and automated injection systems.

Choosing an incorrect concentration or lower grade can lead to severe system failure modes. Inadequate concentration control can cause incomplete neutralization reactions, resulting in out-of-spec pH levels in wastewater discharge systems. Undissolved particulates from poorly dissolved powder can clog fine spray nozzles, ruin expensive membrane filters, and cause premature wear on pump impellers. Furthermore, using unverified technical grades with excessive trace metal impurities can catalyze unwanted side reactions in chemical syntheses or cause corrosion on sensitive metal surfaces instead of targeted passivation.

Chemical Profile

CAS Number
77-92-9
Chemical Formula
C6H8O7
Molecular Weight
192.12 g/mol
Boiling Point
Decomposes (NTP, 1992) °C
Melting Point
307 °F (anhydrous) (NTP, 1992)
Flash Point
100 °C
Specific Gravity
1.54 at 68 °F (USCG, 1999) - Denser than water; will sink
Appearance
Citric acid appears as colorless, odorless crystals with an acid taste. Denser than water. (USCG, 1999)
Solubility
greater than or equal to 100 mg/mL at 72 °F (NTP, 1992)
UN Number
UN1760
Hazard Class
Class 8
Packing Group
III
Proper Shipping Name
Corrosive liquid n.o.s. (Citric acid)
GHS Signal Word
Warning

Values sourced from Alliance Chemical's canonical chemistry registry. Certificate of Analysis (COA) per lot.

Industrial Applications

  • Metal Cleaning and Passivation: Used for removing rust, scale, and metal oxides from stainless steel surfaces to promote protective passivation layer formation.
  • Industrial Water Treatment: Serves as a safe, effective pH adjuster and neutralizer in alkaline wastewater streams before municipal discharge compliance checks.
  • Boiler and Piping Descaling: Dissolves calcium carbonate and iron oxide deposits from industrial heat exchangers, cooling towers, and boiler piping systems.
  • Agricultural Formulations: Acts as a micronutrient chelating agent in liquid fertilizers, improving plant uptake of essential metals like iron and zinc.
  • Textile Auxiliary: Utilized as a pH regulator in textile dyeing and finishing processes to ensure uniform dye uptake on various fabrics.

Hazmat & Shipping

Citric Acid 50% Solution is classified as a regulated hazardous material for transport due to its corrosive properties on certain metals and tissues. It is officially designated as UN1760, Hazard Class 8, Packing Group III, with the Proper Shipping Name Corrosive liquid n.o.s. (Citric acid). Under the Globally Harmonized System (GHS), the signal word is Warning. Compliance with Department of Transportation (DOT) regulations is mandatory for all shipments. This product must be transported in approved containers that resist acidic corrosion to prevent accidental release during transit.

Safety and regulatory compliance demand strict adherence to personal protective equipment (PPE) guidelines based on GHS hazard classifications. Associated hazard statements include H319 for serious eye irritation and H335 for respiratory irritation. Operators must wear chemical-resistant goggles, face shields, and protective gloves during handling to prevent direct contact. In areas with inadequate ventilation where misting may occur, NIOSH-approved respiratory protection is required to prevent inhalation of acidic vapors. Safety Data Sheet (SDS) documents are provided with every order to guide your facility's safety managers in establishing proper handling protocols.

Handling & Storage

Proper storage of Citric Acid 50% Solution is essential to preserve product integrity and prevent equipment damage. Store the chemical in a cool, dry, well-ventilated area, keeping temperatures above 32°F (0°C) to prevent freezing and below 100°F (38°C) to minimize container stress. This solution is highly compatible with high-density polyethylene (HDPE), polypropylene, and fiberglass-reinforced plastic containers, but it is highly corrosive to mild steel, copper, and aluminum. Keep containers tightly closed when not in use and store them away from incompatible substances, particularly strong bases, oxidizing agents, and metal sulfides.

Order & Documentation

Alliance Chemical ensures reliable delivery and complete technical transparency for every shipment. A Certificate of Analysis (COA) is available upon request to verify the exact chemical parameters of your batch, and a Safety Data Sheet (SDS) is provided with every order to support your facility's safety programs. To secure your supply, you can buy directly through our online store or coordinate with our technical sales team for larger volumes. Please Request a Quote for bulk pricing or Download the SDS to review detailed regulatory information before ordering.

Why Buy from Alliance Chemical

Since 1997, Alliance Chemical has supplied premium industrial chemicals from Taylor, Texas under CAGE Code 1LT50, with a COA and SDS included on every order. For industrial use only.

Property Value
Molecular Weight 192.13
Formula C6H8O7
Assay 49-51%
Grade Reagent
Flash Point 230°C (446°F)
Form Liquid
Solubility Soluble in water
Appearance Clear, colorless liquid
Melting Point 153
Boiling Point 175
Specific Gravity 1.06
Industry Food and Beverage, Pharmaceutical, Industrial Cleaning, Laboratory, Personal Care

Frequently Asked Questions About Citric Acid 50% Solution

What is Citric Acid 50% Solution and what is its chemical formula?
Citric Acid 50% Solution is a chemical compound with the molecular formula C6H8O7, registered under CAS Number 77-92-9 by the Chemical Abstracts Service (PubChem), with a molecular weight of 192.12 g/mol. Alliance Chemical supplies Citric Acid 50% Solution in Technical grade for laboratory, industrial, and commercial applications.
What are the physical properties of Citric Acid 50% Solution?
According to the NIOSH Pocket Guide to Chemical Hazards, Citric Acid 50% Solution has a transparent pale liquid, slightly viscous appearance. It has a melting point of 153°C (307.4°F)°C, a boiling point of 175°C (347°F)°C, a flash point of 230°C (446°F). Solubility: Complete water miscibility.
What grade and purity of Citric Acid 50% Solution does Alliance Chemical offer?
Alliance Chemical offers Citric Acid 50% Solution in Technical grade with a purity assay of 50%. Every lot ships with a Certificate of Analysis (COA) and Safety Data Sheet (SDS) prepared in accordance with OSHA Hazard Communication Standard 29 CFR 1910.1200 and GHS Revision 7. Download SDS.
What are common industrial applications of Citric Acid 50% Solution?
Citric Acid 50% Solution has applications in laboratory research, manufacturing, and industrial processing.Alliance Chemical provides the documentation and quality certifications required for use in regulated environments.
What PPE is required when handling Citric Acid 50% Solution?
OSHA-mandated PPE per 29 CFR 1910.132-138:Chemical-resistant gloves (20+ mil neoprene or PVC), full face shield over safety goggles (ANSI Z87.1), acid-resistant apron or chemical suit, closed-toe chemical-resistant footwear. Respiratory protection (organic vapor cartridge) required in areas exceeding PEL/TLV per 29 CFR 1910.134. Emergency eyewash station and safety shower must be accessible within 10 seconds per ANSI Z358.1. Consult the SDS available from Alliance Chemical for complete PPE requirements.
What are the storage requirements for Citric Acid 50% Solution?
Store perOSHA 29 CFR 1910.106: Approved flammable storage cabinet, maximum 60 gallons per cabinet, grounding/bonding required. Temperature range:15-25°C. Segregate from:bases, reactive metals, organic materials. Maximum storage:2-3 years unopened.
What is the emergency spill procedure for Citric Acid 50% Solution?
Emergency response per EPA SPCC (40 CFR 112) and OSHA 29 CFR 1910.120: (1) Alert personnel, evacuate area to 100 feet. (2) Eliminate ignition sources if flammable. (3) Don PPE per SDS Section 8. (4) Stop leak if safe; use emergency shutoffs. (5) Contain with non-combustible absorbent materials, dike with sand/earth. (6)Carefully neutralize with sodium bicarbonate (5-10% solution), monitor exothermic reaction. (7) Collect in DOT-approved containers, label as hazardous waste. Check 40 CFR 302.4 for Reportable Quantity. Emergency: Chemtel 1-800-255-3924 (24/7). Non-emergency: Alliance Chemical 512-365-6838.
What is the DOT shipping classification for Citric Acid 50% Solution?
DOT Classification per 49 CFR 172.101:UNUN1760, Hazard Class8 (Corrosive), Packing GroupII/III. Requires: Hazmat shipping papers (49 CFR 172.200), UN specification packaging (49 CFR 173), hazmat labels (172.400). Alliance Chemical ships all orders in DOT-compliant packaging with proper documentation.
How must Citric Acid 50% Solution waste be disposed?
Disposal per RCRA (40 CFR 261-265):Characteristic waste D002 (Corrosive, pH ≤2 or ≥12.5). Generator requirements: EPA ID number required if >100 kg/month (40 CFR 262.12). Use EPA-permitted Treatment, Storage, Disposal Facility (TSDF). Never discharge to sewer without POTW written approval (40 CFR 403). Container disposal: Triple rinse (40 CFR 261.7), offer for reconditioning/recycling. State regulations may be more stringent — check with your local environmental agency. Consult the Alliance Chemical SDS for product-specific disposal guidance.
Does Alliance Chemical provide an SDS and COA for Citric Acid 50% Solution?
Yes. Alliance Chemical provides a Safety Data Sheet (SDS) and Certificate of Analysis (COA) for every lot of Citric Acid 50% Solution. The SDS is prepared in accordance with OSHA Hazard Communication Standard 29 CFR 1910.1200 and the Globally Harmonized System (GHS) Revision 7, covering all 16 required sections including hazard identification, first aid measures, firefighting measures, handling and storage, exposure controls, and regulatory information. The SDS is available for download directly from this product page. COAs are available upon request by contacting Alliance Chemical at 512-365-6838.