Sodium Hydroxide 25% ACS Grade

Category : Bases

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Sodium Hydroxide 25% ACS Grade

$21.20

Quick Answer

What is Sodium Hydroxide 25% ACS Grade used for, and what should buyers verify before ordering?

Sodium Hydroxide 25% ACS Grade is supplied at 24.5-25.5% in ACS Grade with UN 1824, DOT Class 8 . Buyers should confirm pack size, grade, SDS, COA needs, and freight requirements before purchase.

  • Assay: 24.5-25.5%
  • Grade: ACS Grade
  • UN number: UN 1824
  • DOT class: 8
  • Documents: SDS and lot-specific COA support
  • Shipping: UPS for small packs; LTL/FTL for pails, drums, totes, and bulk orders

Commercial Fulfillment Snapshot

Buy Sodium Hydroxide 25% ACS Grade with faster decisions and fewer back-and-forth emails.

Ships from Taylor, Texas. In-stock orders placed before 1:00 PM CT (Mon-Thu) and before 12:00 PM CT (Fri) typically ship within 1-2 business days. Order online 24/7.

Technical Documents

Lot-specific COA is issued per shipment batch.

Who Buys This
  • Analytical chemistry laboratories
  • Pharmaceutical QA/QC departments
  • Research institutions
  • Chemical synthesis facilities
  • Water treatment labs
Purity / Grade Guide
  • ACS Grade high purity reagent
  • Laboratory & analytical applications
  • 25% solution ready to use
  • Meets ACS specifications
Pack Sizes
  • 1 Quart: lab & small jobs
  • 1 Gallon: shop & maintenance
  • 5 Gallon: production & regular use
  • 15 Gallon: mid-volume operations
  • 55 Gallon: bulk drum
  • 275 Gallon: high-volume tote
  • 330 Gallon: max-volume tote
SDS / COA / TDS
  • SDS included with shipment
  • COA verifies ACS specifications
  • UN 1824 Class 8 packaging
  • DOT compliant hazmat shipping
Small Packs: UPS Ground nationwide for pints, quarts, and gallons.
LTL / FTL: ABF, SEFL, Saia, XPO, and partner carriers for pails, drums, totes, and full truckloads.
Support: Email or call for freight options, hazardous-material routing, and lead-time confirmation.

Product Overview

Sodium Hydroxide 25% ACS Grade is a highly purified aqueous solution of sodium hydroxide — a vital reagent in analytical chemistry, industrial synthesis, and chemical research. Known colloquially as caustic soda, this strongly alkaline liquid solution is prepared with strict adherence to rigorous quality standards — ensuring minimal trace impurities. By maintaining a stable 25% concentration, Alliance Chemical provides a reliable, pre-diluted form of this strong base, eliminating the hazards and thermal energy spikes associated with dissolving solid sodium hydroxide pellets in water.

For industrial facilities, municipal operations, and research laboratories, having access to a pre-formulated 25% concentration is highly advantageous. This precise formulation ensures consistent batch chemistry, predictable reaction rates, and simplified handling during fluid dosing. The solution appears as a colorless and odorless liquid, though it remains significantly denser than water, requiring appropriate agitation and storage setups. Safety remains a primary concern during handling, as this corrosive agent can severely irritate or damage biological tissue upon contact. You can browse our full range of bases or view other sodium hydroxide solutions to find the exact chemical concentration for your facility.

Why This Grade

ACS Grade chemical solutions are manufactured to meet the rigorous specifications established by the American Chemical Society, capping metallic impurities, chlorides, and silicates at exceptionally low parts-per-million levels. In high-precision processes, choosing the correct analytical grade is critical because any excess trace contaminants can poison expensive catalysts or distort spectroscopic baselines. A 25% concentration provides a balance between alkalinity and viscosity, facilitating easier pumping and dosing through automated systems compared to highly viscous 50% solutions.

Selecting an incorrect grade or concentration can introduce severe operational failure modes in critical chemical pathways. For instance, using a technical or industrial grade in analytical testing can yield false positives during trace element detection, potentially invalidating research protocols. Furthermore, attempting to use an incorrect concentration can lead to uncontrolled pH spikes or exothermic boiling, risking equipment failure. Alliance Chemical ensures that our ACS Grade material maintains the stringent purity required to prevent these chemical interferences and system-wide failures.

Chemical Profile

CAS Number
1310-73-2
Chemical Formula
HNaO
Molecular Weight
39.997 g/mol
Boiling Point
greater than 266 °F at 760 mmHg (USCG, 1999)
Melting Point
604 °F (USCG, 1999)
Specific Gravity
1.5 at 68 °F (USCG, 1999) - Denser than water; will sink
Appearance
Sodium hydroxide solution appears as a colorless liquid. More dense than water. Contact may severely irritate skin, eyes, and mucous membranes. Toxic by ingestion. Corrosive to metals and tissue.
Solubility
111 % (NIOSH, 2024)
UN Number
UN1824
Hazard Class
Class 8
Packing Group
II
Proper Shipping Name
SODIUM HYDROXIDE SOLUTION
GHS Signal Word
Danger

Values sourced from Alliance Chemical's canonical chemistry registry. Certificate of Analysis (COA) per lot.

Industrial Applications

  • Chemical Synthesis and pH Regulation: It acts as an essential reactant in neutralizing acidic waste streams and adjusting pH levels in complex organic synthesis pipelines.
  • Water Treatment and Municipal Purification: This solution is extensively utilized for controlling alkalinity and heavy metal precipitation in industrial wastewater treatment facilities.
  • Soap and Detergent Manufacturing: Serving as a primary alkaline source for saponifying fats and oils, it helps produce high-quality cleaning agents and surfactants.
  • Textile Processing and Mercerization: The solution is employed in treating cotton and wood pulp, increasing fiber strength, luster, and dye absorption capacities.
  • Metal Finishing and Etching: Industrial operations use it to degrease, clean, and etch metal surfaces prior to electroplating, anodizing, or protective coating application.

Hazmat & Shipping

Due to its corrosive properties, Sodium Hydroxide 25% ACS Grade is classified as a regulated hazardous material for transportation. Under Department of Transportation guidelines, it is shipped as UN1824, Hazard Class 8, Packing Group II, with the proper shipping name SODIUM HYDROXIDE SOLUTION. The canonical GHS signal word is Danger. Container labels carry GHS pictograms: not applicable. Standard shipping protocols require specialized, heavy-duty packaging to prevent leaks, ensuring safe transport across our national distribution network. Every shipment is accompanied by a comprehensive Safety Data Sheet (SDS) that details spill containment and emergency response procedures.

Appropriate personal protective equipment (PPE) is mandatory when handling this material, specifically dictated by GHS codes H290 (corrosive to metals) and H314 (causes severe skin burns and eye damage). Workers must wear chemical-resistant gloves, splash-resistant goggles, a face shield, and protective garments to avoid any direct skin or eye contact. If an accidental spill occurs, neutralize with a weak acid solution or absorb with non-combustible materials as specified in the SDS. Always maintain a readily accessible eyewash station and safety shower in areas where this corrosive base is processed.

Handling & Storage

Safe handling of this alkaline liquid requires storage in a cool, dry, well-ventilated area, preferably within a temperature range of 60°F to 85°F to prevent freezing or crystallization. Sodium hydroxide is highly corrosive to metals such as aluminum, zinc, and tin, which can release flammable hydrogen gas upon contact; therefore, compatibility with storage tanks made of polyethylene, polypropylene, or lined steel is vital. Keep containers tightly closed to prevent the absorption of atmospheric carbon dioxide, which degrades the solution into sodium carbonate, and store far away from strong acids and oxidizing agents.

Order & Documentation

At Alliance Chemical, we ensure complete transparency and documentation for all our products. A Certificate of Analysis (COA) is available upon request to verify the purity, and a comprehensive Safety Data Sheet (SDS) is provided with every order to support your facility compliance goals. To secure your supply or clarify handling requirements, you can Request a Quote or Download the SDS.

Why Buy from Alliance Chemical

Since 1997, Alliance Chemical has supplied premium industrial chemicals from Taylor, Texas under CAGE Code 1LT50, with a COA and SDS included on every order. For industrial use only.

Property Value
Molecular Weight 40.00
Formula NaOH
Assay 24.5-25.5%
Grade ACS Grade
Form Liquid
Solubility Soluble in water
Appearance Clear, colorless to slightly yellow liquid
Melting Point -15
Boiling Point 1388
Specific Gravity 1.2
Industry Water Treatment, Chemical Manufacturing, Industrial Cleaning, Analytical Chemistry, Food Industry

Frequently Asked Questions About Sodium Hydroxide 25% ACS Grade

What is Sodium Hydroxide 25% ACS Grade and what is its chemical formula?
Sodium Hydroxide 25% ACS Grade is a chemical compound with the molecular formula HNaO, registered under CAS Number 1310-73-2 by the Chemical Abstracts Service (PubChem), with a molecular weight of 39.997 g/mol. Alliance Chemical supplies Sodium Hydroxide 25% ACS Grade in ACS Reagent grade for laboratory, industrial, and commercial applications.
What are the physical properties of Sodium Hydroxide 25% ACS Grade?
According to the NIOSH Pocket Guide to Chemical Hazards, Sodium Hydroxide 25% ACS Grade is supplied as a clear, colorless viscous liquid solution. It has a melting point of 323°C (613.4°F)°C, a boiling point of 1388°C (2530.4°F)°C. The specific gravity is 1.275 relative to water. Solubility: Completely soluble in water, alcohol mixtures.
What grade and purity of Sodium Hydroxide 25% ACS Grade does Alliance Chemical offer?
Alliance Chemical offers Sodium Hydroxide 25% ACS Grade in ACS Reagent grade with a purity assay of 25%. Every lot ships with a Certificate of Analysis (COA) and Safety Data Sheet (SDS) prepared in accordance with OSHA Hazard Communication Standard 29 CFR 1910.1200 and GHS Revision 7. Download SDS.
What are common industrial applications of Sodium Hydroxide 25% ACS Grade?
Sodium Hydroxide 25% ACS Grade serves a wide range of sectors, including Industrial & Manufacturing, and Water & Environmental.Alliance Chemical provides the documentation and quality certifications required for use in regulated environments.
What PPE is required when handling Sodium Hydroxide 25% ACS Grade?
OSHA-mandated PPE per 29 CFR 1910.132-138:Chemical-resistant gloves (20+ mil neoprene or PVC), full face shield over safety goggles (ANSI Z87.1), acid-resistant apron or chemical suit, closed-toe chemical-resistant footwear. Emergency eyewash station and safety shower must be accessible within 10 seconds per ANSI Z358.1. Consult the SDS available from Alliance Chemical for complete PPE requirements.
What are the storage requirements for Sodium Hydroxide 25% ACS Grade?
Store perOSHA 29 CFR 1910.1450: Dedicated corrosives cabinet with secondary containment (110% volume per EPA 40 CFR 264.175). Temperature range:15-25°C. Segregate from:acids, aluminum, zinc. Maximum storage:2-3 years unopened.
What is the emergency spill procedure for Sodium Hydroxide 25% ACS Grade?
Emergency response per EPA SPCC (40 CFR 112) and OSHA 29 CFR 1910.120: (1) Alert personnel, evacuate area to 50 feet. (2) Eliminate ignition sources if flammable. (3) Don PPE per SDS Section 8. (4) Stop leak if safe; use emergency shutoffs. (5) Contain with non-combustible absorbent materials, dike with sand/earth. (6)Neutralize with citric acid or acetic acid (5% solution). (7) Collect in DOT-approved containers, label as hazardous waste. Check 40 CFR 302.4 for Reportable Quantity. Emergency: Chemtel 1-800-255-3924 (24/7). Non-emergency: Alliance Chemical 512-365-6838.
What is the DOT shipping classification for Sodium Hydroxide 25% ACS Grade?
DOT Classification per 49 CFR 172.101:UN1824, Hazard Class8, Packing GroupII. Requires: Hazmat shipping papers (49 CFR 172.200), UN specification packaging (49 CFR 173), hazmat labels (172.400). Alliance Chemical ships all orders in DOT-compliant packaging with proper documentation.
How must Sodium Hydroxide 25% ACS Grade waste be disposed?
Disposal per RCRA (40 CFR 261-265):Characteristic waste D002 (Corrosive, pH ≤2 or ≥12.5). Generator requirements: EPA ID number required if >100 kg/month (40 CFR 262.12). Use EPA-permitted Treatment, Storage, Disposal Facility (TSDF). Never discharge to sewer without POTW written approval (40 CFR 403). Container disposal: Triple rinse (40 CFR 261.7), offer for reconditioning/recycling. State regulations may be more stringent — check with your local environmental agency. Consult the Alliance Chemical SDS for product-specific disposal guidance.
Does Alliance Chemical provide an SDS and COA for Sodium Hydroxide 25% ACS Grade?
Yes. Alliance Chemical provides a Safety Data Sheet (SDS) and Certificate of Analysis (COA) for every lot of Sodium Hydroxide 25% ACS Grade. The SDS is prepared in accordance with OSHA Hazard Communication Standard 29 CFR 1910.1200 and the Globally Harmonized System (GHS) Revision 7, covering all 16 required sections including hazard identification, first aid measures, firefighting measures, handling and storage, exposure controls, and regulatory information. The SDS is available for download directly from this product page. COAs are available upon request by contacting Alliance Chemical at 512-365-6838.