Nitric Acid 40%

Category : Acids

$145.00
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Other Grades & Concentrations

Available in other grades and concentrations:

CAS: 7697-37-2 HNO3
Nitric Acid ACS 69% - 55 Gallon Drum
From $3,982.47
CAS: 7697-37-2 HNO3
Nitric Acid 65%ACS Grade
From $55.00
CAS: 7697-37-2 HNO3
Nitric Acid 25%
From $25.00
CAS: 7697-37-2 HNO3
$145.00
Other Grades & Concentrations

Available in other grades and concentrations:

CAS: 7697-37-2 HNO3
Nitric Acid ACS 69% - 55 Gallon Drum
From $3,982.47
CAS: 7697-37-2 HNO3
Nitric Acid 65%ACS Grade
From $55.00
CAS: 7697-37-2 HNO3
Nitric Acid 25%
From $25.00
CAS: 7697-37-2 HNO3

Nitric Acid 40%

$145.00

Commercial Fulfillment Snapshot

Buy Nitric Acid 40% with faster decisions and fewer back-and-forth emails.

Ships from Taylor, Texas. In-stock orders placed before 1:00 PM CT (Mon-Thu) and before 12:00 PM CT (Fri) typically ship same business day. Order online 24/7.

Technical Documents

Lot-specific COA is issued per shipment batch.

Who Buys This
  • Metal etching & processing facilities
  • Wastewater treatment operators
  • Petroleum refining companies
  • Industrial cleaning services
  • Chemical manufacturing plants
Purity / Grade Guide
  • Industrial & commercial applications
  • 40% concentration verified
  • Purity confirmed by COA
  • Strong oxidizing agent properties
Pack Sizes
  • 1 Liter: lab & bench scale
  • 2.5 Liter: bench & pilot work
  • 55 Gallon: bulk drum
SDS / COA / TDS
  • UN 2031 Class 8 packaging
  • Complete SDS documentation included
  • COA with every shipment
  • Proper hazmat shipping compliance
Small Packs: UPS Ground nationwide for pints, quarts, and gallons.
LTL / FTL: ABF, SEFL, Saia, XPO, and partner carriers for pails, drums, totes, and full truckloads.
Support: Email or call for freight options, hazardous-material routing, and lead-time confirmation.

Why Nitric Acid 40%

Nitric Acid 40% Technical Grade (CAS 7697-37-2) delivers a precisely balanced mid-range concentration tailored for heavy industrial, petroleum refining, and large-scale wastewater operations. Formulated as a clear, colorless liquid, this HNO3 concentration provides powerful oxidative properties while mitigating the severe fuming and extreme exothermic reactions typically associated with diluting stronger acids. Facility operators rely on the 40% solution to streamline metal surface treatments, chemical synthesis, and rapid pH reductions without incurring the higher costs associated with strict analytical certifications. Because it is completely miscible with water, alcohol, and most organic solvents, it integrates rapidly into continuous-flow processes and batch treatment tanks without causing localized pooling or stratification.

Best Applications for This Grade

  • Wastewater pH Normalization: Commonly applied in heavy industrial effluent systems to rapidly neutralize strongly alkaline discharges. The 40% concentration allows operators to meter the acid accurately into large holding tanks, utilizing its complete water miscibility to ensure a uniform pH drop before environmental discharge.
  • Petroleum Equipment Passivation: Acts as a robust oxidizing agent to strip tough organic residues, hydrocarbon scale, and mineral deposits from downstream processing equipment, pipelines, and storage vessels. This prepares the metal surfaces for subsequent operational phases or return to service.
  • Industrial Metal Pickling: Commonly applied in metal finishing facilities to aggressively remove heavy oxide layers, scale, and surface impurities from carbon steel and custom alloys. The mid-range concentration provides rapid etching action prior to coating, electroplating, or structural welding.
  • Heavy-Duty Heat Exchanger Descaling: Dissolves stubborn calcium, magnesium, and rust accumulations within industrial cooling towers and heat exchange networks. Using a pre-diluted 40% solution helps maintenance teams avoid the complex dilution mathematics and intense heat generation associated with stronger concentrations.

When to Choose a Different Grade

  • If your process demands a milder acidic profile to prevent over-etching delicate substrates or requires less aggressive routine pH adjustments, select Nitric Acid 5% or Nitric Acid 20%.
  • If your facility workflow requires a slightly lower mid-range concentration specifically calibrated for continuous chemical manufacturing or custom dilution sequences, consider Nitric Acid 25%.
  • If your operators are performing quantitative analytical laboratory methods, trace-metal analysis, or processes requiring strict compliance with American Chemical Society standards, switch to Nitric Acid 65% ACS Grade.
  • If your organization handles semiconductor manufacturing, microelectronics fabrication, or highly sensitive laboratory procedures demanding strict control over particulate contamination, specify Nitric Acid 70% ACS Grade - Low Particle.
Property Value
Molecular Weight 63.01
Formula HNO3
Assay 39-41%
Grade Reagent
Form Liquid
Solubility Miscible with water
Appearance Clear, colorless liquid
Melting Point -42
Boiling Point 83
Specific Gravity 1.2
Industry Analytical Chemistry, Industrial, Electronics, Environmental, Research

Frequently Asked Questions About Nitric Acid 40%

What is Nitric Acid 40% and what is its chemical formula?
Nitric Acid 40% is a chemical compound with the molecular formula HNO3, registered under CAS Number 7697-37-2 by the Chemical Abstracts Service (PubChem), with a molecular weight of 63.01 g/mol. Alliance Chemical supplies Nitric Acid 40% in Technical grade for laboratory, industrial, and commercial applications.
What are the physical properties of Nitric Acid 40%?
According to the NIOSH Pocket Guide to Chemical Hazards, Nitric Acid 40% is supplied as a clear, colorless liquid. It has a melting point of -42°C (-43.6°F)°C, a boiling point of 83°C (181.4°F)°C. The specific gravity is 1.31 relative to water. Solubility: Miscible with water, alcohol, and most organic solvents.
What grade and purity of Nitric Acid 40% does Alliance Chemical offer?
Alliance Chemical offers Nitric Acid 40% in Technical grade with a purity assay of 40%. Every lot ships with a Certificate of Analysis (COA) and Safety Data Sheet (SDS) prepared in accordance with OSHA Hazard Communication Standard 29 CFR 1910.1200 and GHS Revision 7. Download SDS.
What are common industrial applications of Nitric Acid 40%?
Nitric Acid 40% serves a wide range of sectors, including Energy & Petroleum, Industrial & Manufacturing, and Water & Environmental.Alliance Chemical provides the documentation and quality certifications required for use in regulated environments.
What PPE is required when handling Nitric Acid 40%?
OSHA-mandated PPE per 29 CFR 1910.132-138:Chemical-resistant gloves (20+ mil neoprene or PVC), full face shield over safety goggles (ANSI Z87.1), acid-resistant apron or chemical suit, closed-toe chemical-resistant footwear. Emergency eyewash station and safety shower must be accessible within 10 seconds per ANSI Z358.1. Consult the SDS available from Alliance Chemical for complete PPE requirements.
What are the storage requirements for Nitric Acid 40%?
Store perOSHA 29 CFR 1910.1450: Dedicated corrosives cabinet with secondary containment (110% volume per EPA 40 CFR 264.175). Temperature range:15-25°C. Segregate from:bases, reactive metals, organic materials. Maximum storage:2-3 years unopened.
What is the emergency spill procedure for Nitric Acid 40%?
Emergency response per EPA SPCC (40 CFR 112) and OSHA 29 CFR 1910.120: (1) Alert personnel, evacuate area to 50 feet. (2) Eliminate ignition sources if flammable. (3) Don PPE per SDS Section 8. (4) Stop leak if safe; use emergency shutoffs. (5) Contain with non-combustible absorbent materials, dike with sand/earth. (6)Carefully neutralize with sodium bicarbonate (5-10% solution), monitor exothermic reaction. (7) Collect in DOT-approved containers, label as hazardous waste. Check 40 CFR 302.4 for Reportable Quantity. Emergency: Chemtel 1-800-255-3924 (24/7). Non-emergency: Alliance Chemical 512-365-6838.
What is the DOT shipping classification for Nitric Acid 40%?
DOT Classification per 49 CFR 172.101:UN2031, Hazard Class8, Packing GroupII. Requires: Hazmat shipping papers (49 CFR 172.200), UN specification packaging (49 CFR 173), hazmat labels (172.400). Alliance Chemical ships all orders in DOT-compliant packaging with proper documentation.
How must Nitric Acid 40% waste be disposed?
Disposal per RCRA (40 CFR 261-265):Characteristic waste D002 (Corrosive, pH ≤2 or ≥12.5). Generator requirements: EPA ID number required if >100 kg/month (40 CFR 262.12). Use EPA-permitted Treatment, Storage, Disposal Facility (TSDF). Never discharge to sewer without POTW written approval (40 CFR 403). Container disposal: Triple rinse (40 CFR 261.7), offer for reconditioning/recycling. State regulations may be more stringent — check with your local environmental agency. Consult the Alliance Chemical SDS for product-specific disposal guidance.
Does Alliance Chemical provide an SDS and COA for Nitric Acid 40%?
Yes. Alliance Chemical provides a Safety Data Sheet (SDS) and Certificate of Analysis (COA) for every lot of Nitric Acid 40%. The SDS is prepared in accordance with OSHA Hazard Communication Standard 29 CFR 1910.1200 and the Globally Harmonized System (GHS) Revision 7, covering all 16 required sections including hazard identification, first aid measures, firefighting measures, handling and storage, exposure controls, and regulatory information. The SDS is available for download directly from this product page. COAs are available upon request by contacting Alliance Chemical at 512-365-6838.