Citric Acid 25% Solution

Category : Acids

$19.93
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Other Grades & Concentrations

Available in other grades and concentrations:

CAS: 5949-29-1 C6H8O7·H2O
CAS: 77-92-9 C6H8O7
CAS: 5949-29-1 C6H8O7·H2O
Citric Acid Anhydrous - Food Grade
From $20.00
CAS: 77-92-9 C6H8O7
$19.93
Other Grades & Concentrations

Available in other grades and concentrations:

CAS: 5949-29-1 C6H8O7·H2O
CAS: 77-92-9 C6H8O7
CAS: 5949-29-1 C6H8O7·H2O
Citric Acid Anhydrous - Food Grade
From $20.00
CAS: 77-92-9 C6H8O7

Citric Acid 25% Solution

$19.93

Commercial Fulfillment Snapshot

Buy Citric Acid 25% Solution with faster decisions and fewer back-and-forth emails.

Ships from Taylor, Texas. In-stock orders placed before 1:00 PM CT (Mon-Thu) and before 12:00 PM CT (Fri) typically ship same business day. Order online 24/7.

Technical Documents

Lot-specific COA is issued per shipment batch.

Who Buys This
  • Food & beverage processors
  • Pharmaceutical manufacturers
  • Industrial cleaning companies
  • Cosmetic & personal care makers
  • Nutritional supplement producers
Purity / Grade Guide
  • Industrial & lab applications
  • Verified purity, COA included
  • Suitable for commercial use
  • 25% concentration for easy handling
Pack Sizes
  • 1 Quart: lab & small jobs
  • 1 Gallon: shop & maintenance
  • 5 Gallon: production & regular use
  • 15 Gallon: mid-volume operations
  • 55 Gallon: bulk drum
  • 275 Gallon: high-volume tote
  • 330 Gallon: max-volume tote
SDS / COA / TDS
  • SDS
  • COA
  • Non-regulated ground shipment
  • Warning label Class 8
Small Packs: UPS Ground nationwide for pints, quarts, and gallons.
LTL / FTL: ABF, SEFL, Saia, XPO, and partner carriers for pails, drums, totes, and full truckloads.
Support: Email or call for freight options, hazardous-material routing, and lead-time confirmation.

Why Citric Acid 25% Solution

Citric Acid 25% Solution (CAS: 77-92-9) Technical Grade delivers immediate, ready-to-meter acidity and chelation without the blending time or dust exposure associated with dry powders. By providing a stable 25% concentration, this clear, colorless liquid ensures consistent dosing accuracy for precise pH control and the complexing of metal ions. Represented by the chemical formula C6H8O7, this industrial-strength organic acid readily replaces harsher mineral acids, such as hydrochloric or nitric acid, in processes sensitive to aggressive base metal corrosion. Because it is fully soluble in water, alcohol, and ether, the solution integrates rapidly into existing fluid streams. This specific concentration prevents drastic pH swings in sensitive biological wastewater operations and mitigates the risk of over-acidification during routine industrial surface treatments.

Best Applications for This Grade

  • Commonly applied in metal finishing and passivation lines as an effective chelating agent. The 25% solution complexes free iron and removes surface oxides from stainless steel parts, promoting a passive oxide layer without introducing the hazardous fumes or severe pitting risks associated with higher-concentration mineral acids.
  • Commonly applied in industrial wastewater treatment facilities to neutralize alkaline effluent and control pH prior to discharge. Its organic acid profile allows operators to precipitate heavy metals safely and meet strict environmental discharge parameters without adding excessive chloride or sulfate loads to the water stream.
  • Commonly applied in the formulation of industrial descaling solutions and boiler maintenance chemicals. The organic acidity efficiently breaks down calcium carbonate, rust, and stubborn mineral deposits within heat exchangers and piping infrastructure, restoring thermal efficiency while remaining less corrosive to underlying metallurgy than concentrated hydrochloric acid.
  • Commonly applied in textile processing and industrial dyeing operations as a reliable pH buffer. Maintaining precise acidity levels is critical for consistent dye uptake and colorfastness on fabric substrates, and the pre-mixed 25% liquid eliminates the risk of undissolved particulate spotting the finished textiles.
  • Commonly applied in concrete and cement retarder formulations. The solution slows the hydration and setting time of concrete mixtures, which is particularly critical when pouring large volumes in elevated temperatures where rapid curing could lead to structural weaknesses or cracking.

When to Choose a Different Grade

  • If bulk industrial processing demands a higher active chemical ratio to reduce freight costs and allow for expansive on-site dilution schedules → Citric Acid 50% Solution.
  • If heavy-duty metal pickling, severe rust removal, or intense pH reduction workflows require a stronger acidic profile than a predefined 25% baseline dilution can support → Citric Acid 50% Solution.
Property Value
Molecular Weight 192.13
Formula C6H8O7
Assay 24.5-25.5%
Grade Technical
Form Liquid
Solubility Soluble in water
Appearance Clear, colorless liquid
Melting Point 153
Boiling Point 152
Specific Gravity 1.05
Industry Food and Beverage, Pharmaceutical, Industrial Cleaning, Health and Nutrition, Personal Care

Frequently Asked Questions About Citric Acid 25% Solution

What is Citric Acid 25% Solution and what is its chemical formula?
Citric Acid 25% Solution is a chemical compound with the molecular formula C6H8O7, registered under CAS Number 77-92-9 by the Chemical Abstracts Service (PubChem), with a molecular weight of 192.12 g/mol. Alliance Chemical supplies Citric Acid 25% Solution in Technical grade for laboratory, industrial, and commercial applications.
What are the physical properties of Citric Acid 25% Solution?
According to the NIOSH Pocket Guide to Chemical Hazards, Citric Acid 25% Solution has a clear, colorless liquid appearance. It has a melting point of 153°C (307.4°F)°C, a boiling point of 152°C (305.6°F)°C. Solubility: Soluble in water, alcohol, and ether.
What grade and purity of Citric Acid 25% Solution does Alliance Chemical offer?
Alliance Chemical offers Citric Acid 25% Solution in Technical grade with a purity assay of 25%. Every lot ships with a Certificate of Analysis (COA) and Safety Data Sheet (SDS) prepared in accordance with OSHA Hazard Communication Standard 29 CFR 1910.1200 and GHS Revision 7. Download SDS.
What are common industrial applications of Citric Acid 25% Solution?
Citric Acid 25% Solution has applications in laboratory research, manufacturing, and industrial processing.Alliance Chemical provides the documentation and quality certifications required for use in regulated environments.
What PPE is required when handling Citric Acid 25% Solution?
OSHA-mandated PPE per 29 CFR 1910.132-138:Chemical-resistant gloves (20+ mil neoprene or PVC), full face shield over safety goggles (ANSI Z87.1), acid-resistant apron or chemical suit, closed-toe chemical-resistant footwear. Emergency eyewash station and safety shower must be accessible within 10 seconds per ANSI Z358.1. Consult the SDS available from Alliance Chemical for complete PPE requirements.
What are the storage requirements for Citric Acid 25% Solution?
Store perOSHA 29 CFR 1910.1450: Dedicated corrosives cabinet with secondary containment (110% volume per EPA 40 CFR 264.175). Temperature range:15-25°C. Segregate from:bases, reactive metals, organic materials. Maximum storage:2-3 years unopened.
What is the emergency spill procedure for Citric Acid 25% Solution?
Emergency response per EPA SPCC (40 CFR 112) and OSHA 29 CFR 1910.120: (1) Alert personnel, evacuate area to 50 feet. (2) Eliminate ignition sources if flammable. (3) Don PPE per SDS Section 8. (4) Stop leak if safe; use emergency shutoffs. (5) Contain with non-combustible absorbent materials, dike with sand/earth. (6)Carefully neutralize with sodium bicarbonate (5-10% solution), monitor exothermic reaction. (7) Collect in DOT-approved containers, label as hazardous waste. Check 40 CFR 302.4 for Reportable Quantity. Emergency: Chemtel 1-800-255-3924 (24/7). Non-emergency: Alliance Chemical 512-365-6838.
What is the DOT shipping classification for Citric Acid 25% Solution?
DOT Classification per 49 CFR 172.101:See SDS Section 14 for specific UN number, Hazard Class8 (Corrosive), Packing GroupII/III. Requires: Hazmat shipping papers (49 CFR 172.200), UN specification packaging (49 CFR 173), hazmat labels (172.400). Alliance Chemical ships all orders in DOT-compliant packaging with proper documentation.
How must Citric Acid 25% Solution waste be disposed?
Disposal per RCRA (40 CFR 261-265):Characteristic waste D002 (Corrosive, pH ≤2 or ≥12.5). Generator requirements: EPA ID number required if >100 kg/month (40 CFR 262.12). Use EPA-permitted Treatment, Storage, Disposal Facility (TSDF). Never discharge to sewer without POTW written approval (40 CFR 403). Container disposal: Triple rinse (40 CFR 261.7), offer for reconditioning/recycling. State regulations may be more stringent — check with your local environmental agency. Consult the Alliance Chemical SDS for product-specific disposal guidance.
Does Alliance Chemical provide an SDS and COA for Citric Acid 25% Solution?
Yes. Alliance Chemical provides a Safety Data Sheet (SDS) and Certificate of Analysis (COA) for every lot of Citric Acid 25% Solution. The SDS is prepared in accordance with OSHA Hazard Communication Standard 29 CFR 1910.1200 and the Globally Harmonized System (GHS) Revision 7, covering all 16 required sections including hazard identification, first aid measures, firefighting measures, handling and storage, exposure controls, and regulatory information. The SDS is available for download directly from this product page. COAs are available upon request by contacting Alliance Chemical at 512-365-6838.