Potassium Hydroxide (KOH)

Category : Bases

$17.20
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$17.20

Potassium Hydroxide (KOH)

$17.20
  • Description
  • Product Documents
  • Chemical Profile

Product Overview

Potassium Hydroxide (KOH), commonly known as Caustic Potash or Potash Lye, is a strong inorganic base supplied as white, Technical Grade flakes. This material provides a highly soluble source of hydroxide ions for demanding industrial environments. It is essential for pH adjustment, neutralization, and base-catalyzed chemical reactions. Unlike sodium-based alkalis, Potassium Hydroxide offers higher solubility and prevents the formation of insoluble sodium salts in specific formulations.

Engineered for industrial consistency, this Technical Grade KOH (typical 90% assay) ensures reliable alkalinity for chemical synthesis, soap manufacturing (soft soaps), and electrolyte production. The controlled impurity profile minimizes scaling and interference in downstream processing. It serves as a primary reagent in degreasing agents, biodiesel production, and the manufacturing of potassium-based chemicals.

Key Properties

  • Appearance: White, solid flakes
  • Chemical Formula: KOH
  • CAS Number: 1310-58-3
  • Grade: Technical
  • Assay (wt %): 85–95 (typical 90)
  • Molecular Weight: 56.11 g/mol
  • Specific Gravity: 1.15 (typical at 20°C)
  • Solubility: Highly soluble in water, alcohol, and glycerol
  • Melting Point: ~360°C
  • Alkalinity: pKa 14.0 (Strong Base)

Common Applications

  • pH Control & Water Treatment: Used to neutralize acidic waste streams and adjust alkalinity in industrial water systems where sodium limits apply.
  • Soap & Detergent Manufacturing: Acts as the primary saponifying agent for soft soaps, liquid soaps, and specialized detergents, offering superior solubility compared to caustic soda.
  • Chemical Synthesis: Functions as a strong base for deprotonation, ester hydrolysis, and the production of potassium salts (e.g., Potassium Carbonate, Potassium Phosphates).
  • Batteries & Electronics: Serves as a conductive electrolyte in alkaline batteries and various electrochemical cells.
  • Cleaning & Degreasing: Formulated into heavy-duty industrial cleaners for removing oils, greases, and organic residues from stainless steel and process equipment.
  • Biodiesel Production: Utilized as a catalyst in the transesterification process to convert fats and oils into biodiesel.

Safety & Handling

DANGER: Corrosive Material. Potassium Hydroxide causes severe skin burns and eye damage. Store in a cool, dry, well-ventilated area away from moisture, acids, and reactive metals (aluminum, zinc, tin). This product is hygroscopic and will absorb water from the air; keep containers tightly sealed when not in use.

Required PPE: Wear chemical-resistant gloves, full-face splash shield/goggles, and impervious protective clothing. Ensure an eyewash station and safety shower are immediately available.

Related Products

Property Value
Molecular Weight 56.11 g/mol
Formula KOH
Grade Technical
Flash Point N/A
Form Solid
Solubility Highly water-soluble, moderate alcohol solubility
Appearance White crystalline powder
Melting Point 360 °C
Boiling Point 1320 °C
Specific Gravity 2.044
Industry Industrial, Chemical, Wastewater

Frequently Asked Questions About Potassium Hydroxide (KOH)

What is Potassium Hydroxide (KOH) and what is its chemical formula?
Potassium Hydroxide (KOH) is a chemical compound with the molecular formula KOH, registered under CAS Number 1310-58-3 by the Chemical Abstracts Service (PubChem), with a molecular weight of 56.11 g/mol. Alliance Chemical supplies Potassium Hydroxide (KOH) in Technical grade for laboratory, industrial, and commercial applications.
What are the physical properties of Potassium Hydroxide (KOH)?
According to the NIOSH Pocket Guide to Chemical Hazards, Potassium Hydroxide (KOH) is supplied as a solid with a white crystalline powder appearance. It has a melting point of 360°C, a boiling point of 1320°C, a flash point of N/A. The specific gravity is 2.044 relative to water. Solubility: Highly water-soluble, moderate alcohol solubility.
What grade and purity of Potassium Hydroxide (KOH) does Alliance Chemical offer?
Alliance Chemical offers Potassium Hydroxide (KOH) in Technical grade. Every lot ships with a Certificate of Analysis (COA) and Safety Data Sheet (SDS) prepared in accordance with OSHA Hazard Communication Standard 29 CFR 1910.1200 and GHS Revision 7. Download SDS.
What are common industrial applications of Potassium Hydroxide (KOH)?
Potassium Hydroxide (KOH) serves a wide range of sectors, including Industrial, Chemical, and Wastewater.Alliance Chemical provides the documentation and quality certifications required for use in regulated environments.
What PPE is required when handling Potassium Hydroxide (KOH)?
OSHA-mandated PPE per 29 CFR 1910.132-138:Chemical-resistant gloves (20+ mil neoprene or PVC), full face shield over safety goggles (ANSI Z87.1), acid-resistant apron or chemical suit, closed-toe chemical-resistant footwear. Respiratory protection (organic vapor cartridge) required in areas exceeding PEL/TLV per 29 CFR 1910.134. Emergency eyewash station and safety shower must be accessible within 10 seconds per ANSI Z358.1. Consult the SDS available from Alliance Chemical for complete PPE requirements.
What are the storage requirements for Potassium Hydroxide (KOH)?
Store perOSHA 29 CFR 1910.106: Approved flammable storage cabinet, maximum 60 gallons per cabinet, grounding/bonding required. Temperature range:15-25°C. Segregate from:acids, aluminum, zinc. Maximum storage:2-3 years unopened.
What is the emergency spill procedure for Potassium Hydroxide (KOH)?
Emergency response per EPA SPCC (40 CFR 112) and OSHA 29 CFR 1910.120: (1) Alert personnel, evacuate area to 100 feet. (2) Eliminate ignition sources if flammable. (3) Don PPE per SDS Section 8. (4) Stop leak if safe; use emergency shutoffs. (5) Contain with non-combustible absorbent materials, dike with sand/earth. (6)Neutralize with citric acid or acetic acid (5% solution). (7) Collect in DOT-approved containers, label as hazardous waste. Check 40 CFR 302.4 for Reportable Quantity. Emergency: Chemtel 1-800-255-3924 (24/7). Non-emergency: Alliance Chemical 512-365-6838.
What is the DOT shipping classification for Potassium Hydroxide (KOH)?
DOT Classification per 49 CFR 172.101:See SDS Section 14 for specific UN number, Hazard Class8 (Corrosive), Packing GroupII/III. Requires: Hazmat shipping papers (49 CFR 172.200), UN specification packaging (49 CFR 173), hazmat labels (172.400). Alliance Chemical ships all orders in DOT-compliant packaging with proper documentation.
How must Potassium Hydroxide (KOH) waste be disposed?
Disposal per RCRA (40 CFR 261-265):Characteristic waste D002 (Corrosive, pH ≤2 or ≥12.5). Generator requirements: EPA ID number required if >100 kg/month (40 CFR 262.12). Use EPA-permitted Treatment, Storage, Disposal Facility (TSDF). Never discharge to sewer without POTW written approval (40 CFR 403). Container disposal: Triple rinse (40 CFR 261.7), offer for reconditioning/recycling. State regulations may be more stringent — check with your local environmental agency. Consult the Alliance Chemical SDS for product-specific disposal guidance.
Does Alliance Chemical provide an SDS and COA for Potassium Hydroxide (KOH)?
Yes. Alliance Chemical provides a Safety Data Sheet (SDS) and Certificate of Analysis (COA) for every lot of Potassium Hydroxide (KOH). The SDS is prepared in accordance with OSHA Hazard Communication Standard 29 CFR 1910.1200 and the Globally Harmonized System (GHS) Revision 7, covering all 16 required sections including hazard identification, first aid measures, firefighting measures, handling and storage, exposure controls, and regulatory information. The SDS is available for download directly from this product page. COAs are available upon request by contacting Alliance Chemical at 512-365-6838.