Sodium Metabisulfite - Technical Grade

CAS
7681-57-4
Formula
Na2O5S2
$27.50
$27.50

1 Pack (2 lbs.)

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Sodium Metabisulfite Technical Grade in a 2-lb white plastic bottle from Alliance Chemical
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Quantity
In Stock — ready to ship from our Taylor, TX warehouse Order by Mon-Thu 2 PM CT / Fri 12 PM CT — ships in 1–2 business days If it’s listed, it’s on our shelf. No backorders, no 4-week lead times. Why
Temporarily unavailable This item isn’t ready to ship right now. Call 512-365-6838 for restock timing.
  • No hazmat fees from us — you pay the carrier’s shipping rate, at cost
  • Drums, totes & pails ship LTL freight — liftgate delivery available
  • PO / Net 30 for approved businesses · tax-exempt ordering supported

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Sodium Metabisulfite - Technical Grade

$27.50
Ball-and-stick model of Sodium metabisulfite

Sodium Metabisulfite

Technical grade is the industrial tier: supplied for coatings, adhesives, cleaning, degreasing and general process work where certified trace-impurity limits are not written into the protocol. A lot-specific Certificate of Analysis is available on request. If your SOP names a higher analytical tier, specify that grade when you order — this product is not supplied to those specifications.

Also known as
sodium pyrosulfite · sodium disulfite · SMBS
CAS number
7681-57-4
Formula
Na2O5S2
Molecular weight
190.11 g/mol
Grade
Technical Grade
Boiling point
Decomposes

Hazards

Signal word Danger

  • Corrosive
  • Irritant

Summary only. Read the SDS and the container label for complete hazard and handling information.

SDS also in

Who uses it

Water treatment operators running dechlorination systems, textile processors using reduction dyeing, photographic labs and industrial maintenance teams that need a reliable, cost-effective reducing agent for process chemistry.

  • Aerial view of two circular clarifier basins with bridge walkways at a wastewater treatment plant
    Water & Wastewater

Representative industry photos.

Product quick facts

CAS 7681-57-4Na2O5S2

Sodium Metabisulfite - Technical Grade (CAS 7681-57-4) is a Technical Grade solid with molecular formula Na2O5S2 and a molecular weight of 190.11 g/mol, for industrial and manufacturing applications. It is also known as sodium pyrosulfite, sodium disulfite and SMBS. Alliance Chemical supplies this product in 3 container sizes from 2 lbs. to 50 Lbs. (12 pack options) with 1-2 business day shipping from Taylor, TX on in-stock orders, plus SDS and lot-specific Certificate of Analysis.

  • Pack sizes 3 container sizes (2 lbs. to 50 Lbs.) · 12 pack options
  • Purity / spec Technical Grade
  • Lead time In-stock orders placed by Mon-Thu 2 PM CT / Fri 12 PM CT typically ship within 1-2 business days.
  • Regional availability View state-by-state shipping pages
Forklift moving pallets in a warehouse

Stock footage.

How it ships.

Regulated products are packed, marked, and labeled for hazmat transport, from one quart to a pallet of drums.

  • Most stocked orders ship in 1–2 business daysOrder cutoff: Mon-Thu 2 PM CT / Fri 12 PM CT
  • Hazmat packing, marking, and labelingPacked by staff trained under DOT rule 49 CFR 172.704
  • UPS Ground for bottles, jugs, and up to three pailsLTL freight for four or more pails, drums, and totes. Liftgate on request.
  • Ships with
  • UPS
  • FedEx Freight
  • ABF Freight
  • R+L Carriers
  • Saia
  • Southeastern Freight Lines
  • XPO

Buying for a company or agency?

Pay by card at the listed price, or order on Net 30 terms once your credit is approved. For NSN and contract requirements, send an RFQ.

CAGE code
1LT50
UEI
DCTCZDY3BLD3
Primary NAICS
424690
Ownership
Woman-Owned
Federal supply
DLA Supplier
Terms
Net 30 on approved credit, W-9 on request
Gloved hands strapping four blue chemical drums to a pallet at a warehouse loading dock
Illustration.

Safety data sheets and certificates.

Find an SDS or TDS by product name or CAS number. Certificates of analysis are free on request.

Find an SDS or COA

Selected organizations we've supplied

Logos identify supplied organizations; no endorsement or partnership is implied.

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Product Overview

Sodium Metabisulfite Technical Grade is a white crystalline powder that functions as a strong reducing agent across water treatment, dechlorination and industrial chemical processes. Also known as Sodium Pyrosulfite or Disodium Metabisulfite (CAS 7681-57-4), it dissolves readily in water and releases sulfur dioxide — the active species behind most of its industrial utility.

This Technical Grade product is offered in pack sizes from 2 lbs to 55 lbs bags, serving bench-scale trials through ongoing production use. Alliance Chemical provides SDS, COA and TDS documentation for every lot ordered.

Why This Grade

Technical Grade sodium metabisulfite is the standard procurement choice for water treatment operators, industrial process engineers and maintenance teams whose applications do not require a tighter analytical specification. It delivers the reducing power needed for dechlorination, chemical reduction and process antioxidant use at a lower cost point than technical or analytical grades.

Buyers running municipal or industrial dechlorination systems, textile dye-reduction baths, or photographic processing lines typically specify Technical Grade because the work demands consistent reducing activity — not a narrow assay window tied to a published analytical standard. If your process does require documentation against a specific purity monograph, ask our team about alternative grades.

Chemical Profile

Sodium metabisulfite (Na2O5S2, molecular weight 190.11 g/mol, CAS 7681-57-4) appears as a white crystalline or powder solid with a slight sulfur odor. In the presence of even trace moisture it develops the unmistakable sharp odor of sulfur dioxide — a useful field indicator that the container seal has been compromised. The solid is denser than water at a density of 1.4 and dissolves readily, with a water solubility of 54%. It is noncombustible under normal conditions but may decompose at elevated temperatures to release toxic sulfur oxide and sodium oxide fumes.

Industrial Applications

Sodium metabisulfite's value in industry traces to one core property: it is a fast-acting reducing agent that liberates sulfur dioxide on contact with water. That chemistry drives its use across several sectors.

  • Water Treatment & Dechlorination— Municipal and industrial water systems use sodium metabisulfite to neutralize residual chlorine before discharge or reuse. In dechlorination applications it reacts rapidly with free and combined chlorine, converting them to chloride ions. This is standard practice ahead of membrane systems, boiler feed lines and permitted outfalls.
  • Chemical Reduction— As a general-purpose industrial reducing agent, sodium metabisulfite participates in processes where controlled reduction of oxidized species is required — from hexavalent chromium reduction in wastewater streams to oxygen scavenging in closed-loop systems.
  • Photography— Darkroom and large-format photographic processing rely on sodium metabisulfite as a preservative and mild acidifier in stop baths and fixing solutions, where it controls oxidation of developing agents.
  • Textile Processing— In dyeing operations, sodium metabisulfite serves as a reducing agent in vat dye application and discharge printing, where it strips color in controlled patterns or prepares fibers for dye uptake.
  • Chemical Synthesis— Process-scale chemical operations use sodium metabisulfite as a reducing agent and sulfonation source in the production of intermediates and specialty compounds.

Handling & Storage

Sodium metabisulfite carries aDangersignal word under its GHS classification (per the product's GHS classification). The two primary hazard statements are H302 — harmful if swallowed — and H318 — causes serious eye damage (per the product's GHS classification). Operators should wear chemical splash goggles, impervious gloves and a dust respirator when handling the dry powder. In enclosed spaces, ensure adequate ventilation — the sulfur dioxide released on contact with moisture or acids is a respiratory irritant.

Store in a cool, dry area in tightly sealed containers. Sodium metabisulfite is hygroscopic and will degrade on moisture exposure, losing reducing activity and generating SO2off-gas. Keep it isolated from strong acids, strong oxidizers and bases. Containers that have been opened should be resealed promptly and consumed within a reasonable timeframe to preserve quality.

Hazmat & Shipping

Sodium Metabisulfite Technical Grade is not classified as a DOT hazardous material for transport — it carries no UN number, hazard class, or packing group assignment (per 49 CFR 172.101). Shipments do not require a DOT hazmat placard. Carriers may still apply their own handling or routing requirements based on the product's GHS hazard classification and receivers should verify local storage and permitting obligations independently. All shipping and transport guidance for this product has been reviewed by Andre Taki, DOT Hazmat Specialist.

Documentation

Every order of Sodium Metabisulfite Technical Grade ships with a Safety Data Sheet (SDS) in English. A lot-specific Certificate of Analysis (COA) is available on request, documenting analytical results for the production lot you receive. A Technical Data Sheet (TDS) is also provided for specification reference. Contact our team if you need documentation in advance of placing an order.

Why Buy from Alliance Chemical

This product ships with full lot documentation — SDS, COA and TDS — because industrial buyers selecting a reducing agent need verifiable data, not marketing language. Alliance Chemical has served over 55,000 customers since 1998, operating from our warehouse at 204 S Edmond St, Taylor, Texas 76574. Shipping and handling protocols for this product are reviewed by Andre Taki, DOT Hazmat Specialist, so your order arrives with the correct classification, packaging and paperwork.

Frequently Asked Questions About Sodium Metabisulfite - Technical Grade

What is Sodium Metabisulfite Technical Grade used for?
It is primarily used in industrial settings for water treatment (dechlorination and oxygen scavenging), photographic developing, textile processing (as an antichlor), and mining flotation processes.
Is this product Food Grade?
This listing is for Technical Grade material intended for industrial applications. For food applications, please verify specs or purchase our specific Food Grade option linked in the related products section.
What is Sodium Metabisulfite - Technical Grade and what is its chemical formula?
Sodium Metabisulfite - Technical Grade is listed under CAS 7681-57-4 (PubChem reference search). The catalog formula is Na2O5S2. The listed molecular weight is 190.11 g/mol. For solutions and blends, identity values may describe a constituent; consult the product SDS for composition.
What are the physical properties of Sodium Metabisulfite - Technical Grade?
Catalog reference information for Sodium Metabisulfite - Technical Grade: form: Solid; melting point: greater than 302 °F (Decomposes); boiling point: Decomposes; reference values may describe a pure substance rather than the supplied concentration or blend. Confirm applicable conditions and specifications in the product documents; these values are not batch test results.
What grade and purity of Sodium Metabisulfite - Technical Grade does Alliance Chemical offer?
Alliance Chemical lists Sodium Metabisulfite - Technical Grade in Technical Grade. Check the product specification for the measurement basis and acceptance limits. A grade label alone does not establish certification or suitability for a regulated application. For batch results, request a COA using the product name and lot number.
What are common industrial applications of Sodium Metabisulfite - Technical Grade?
Catalog industry categories for Sodium Metabisulfite - Technical Grade include Water & Wastewater. To evaluate it for your process, compare the listed grade, concentration and product specifications with your requirements. Contact Alliance Chemical to confirm any application-specific documentation or certification before ordering.
What are the hazards of Sodium Metabisulfite - Technical Grade and where do I find handling guidance?
Per its GHS classification (SDS Section 2), Sodium Metabisulfite - Technical Grade carries the signal word Danger and the following hazard statements: H302 (Harmful if swallowed); H318 (Causes serious eye damage). Product-specific first aid, fire-fighting, spill response, handling, storage, exposure controls/PPE, and disposal guidance are in SDS Sections 4-8 and 13 — always consult the SDS before use. Download the SDS.
How must Sodium Metabisulfite - Technical Grade waste be disposed?
Consult SDS Section 13 for disposal information for Sodium Metabisulfite - Technical Grade. Disposal requirements depend on the resulting waste, contamination and location. Have your site's responsible waste professional determine the appropriate waste classification and disposal method. View the SDS.
Does Alliance Chemical provide an SDS and COA for Sodium Metabisulfite - Technical Grade?
Search the document library for Sodium Metabisulfite - Technical Grade. The SDS is also available here. A sample COA describes specifications and does not establish the results for your shipment. To request a lot-specific COA or confirm document availability, contact Alliance Chemical with the product name and lot number.